Exceptional TcO4                         − sorption capacity and highly efficient ReO4                         − luminescence sensing by Zr4+ MOFs

Sofia Rapti; Stavros A. Diamantis; Argyro Dafnomili; Anastasia Pournara; Euaggelia Skliri; Gerasimos S. Armatas; Athanassios C. Tsipis; Ioannis Spanopoulos; Christos D. Malliakas; Mercouri G. Kanatzidis; John C. Plakatouras; Fotini Noli; Theodore Lazarides; Manolis J. Manos

doi:10.1039/c8ta07901c

Exceptional TcO₄ ⁻ sorption capacity and highly efficient ReO₄ ⁻ luminescence sensing by Zr⁴⁺ MOFs

Sofia Rapti, Stavros A. Diamantis, Argyro Dafnomili, Anastasia Pournara, Euaggelia Skliri, Gerasimos S. Armatas, Athanassios C. Tsipis, Ioannis Spanopoulos, Christos D. Malliakas, Mercouri G. Kanatzidis, John C. Plakatouras^*, Fotini Noli, Theodore Lazarides, Manolis J. Manos

^*Corresponding author for this work

Chemistry

Research output: Contribution to journal › Article › peer-review

43 Scopus citations

Abstract

The sorption properties of [Zr₆O₄(OH)₄(NH₃ ⁺-BDC)₆]Cl₆·xH₂O (MOR-1) and H₁₆[Zr₆O₁₆(H₂PATP)₄]Cl₈·xH₂O (MOR-2) towards ReO₄ ⁻ and TcO₄ ⁻ were studied in detail. Both MOR-1 and MOR-2 are very effective sorbents for ReO₄ ⁻ and TcO₄ ⁻ anions, with MOR-2 showing the highest sorption capacity (up to 4.1 ± 0.4 mmol g⁻¹) among the known metal organic materials. Importantly, the exceptional sorption capacity of MOR-2 is retained even under conditions simulating acidic nuclear waste. In addition, MOR-1 and MOR-2 exhibit selective luminescence ReO₄ ⁻ sensing properties, demonstrated for the first time for MOF materials.

Original language	English (US)
Pages (from-to)	20813-20821
Number of pages	9
Journal	Journal of Materials Chemistry A
Volume	6
Issue number	42
DOIs	https://doi.org/10.1039/c8ta07901c
State	Published - 2018

ASJC Scopus subject areas

Chemistry(all)
Renewable Energy, Sustainability and the Environment
Materials Science(all)

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10.1039/c8ta07901c

Cite this

Rapti, S., Diamantis, S. A., Dafnomili, A., Pournara, A., Skliri, E., Armatas, G. S., Tsipis, A. C., Spanopoulos, I., Malliakas, C. D., Kanatzidis, M. G., Plakatouras, J. C., Noli, F., Lazarides, T., & Manos, M. J. (2018). Exceptional TcO₄ ⁻ sorption capacity and highly efficient ReO₄ ⁻ luminescence sensing by Zr⁴⁺ MOFs. Journal of Materials Chemistry A, 6(42), 20813-20821. https://doi.org/10.1039/c8ta07901c

@article{bfebdb14aca5466981452888f919cf32,

title = "Exceptional TcO4 − sorption capacity and highly efficient ReO4 − luminescence sensing by Zr4+ MOFs",

abstract = "The sorption properties of [Zr6O4(OH)4(NH3 +-BDC)6]Cl6·xH2O (MOR-1) and H16[Zr6O16(H2PATP)4]Cl8·xH2O (MOR-2) towards ReO4 − and TcO4 − were studied in detail. Both MOR-1 and MOR-2 are very effective sorbents for ReO4 − and TcO4 − anions, with MOR-2 showing the highest sorption capacity (up to 4.1 ± 0.4 mmol g−1) among the known metal organic materials. Importantly, the exceptional sorption capacity of MOR-2 is retained even under conditions simulating acidic nuclear waste. In addition, MOR-1 and MOR-2 exhibit selective luminescence ReO4 − sensing properties, demonstrated for the first time for MOF materials.",

author = "Sofia Rapti and Diamantis, {Stavros A.} and Argyro Dafnomili and Anastasia Pournara and Euaggelia Skliri and Armatas, {Gerasimos S.} and Tsipis, {Athanassios C.} and Ioannis Spanopoulos and Malliakas, {Christos D.} and Kanatzidis, {Mercouri G.} and Plakatouras, {John C.} and Fotini Noli and Theodore Lazarides and Manos, {Manolis J.}",

note = "Funding Information: The powder X-ray diffraction and thermal analysis units of the Network of Research Supporting Laboratories at the University of Ioannina are acknowledged. The post-doctoral research of Dr A. Pournara was implemented with IKY scholarship, funded by the Act “Supporting Post-Academic Researchers” from the resources of the NF “Human Resources Development, Education and Lifelong Learning” with Priority Axes 6, 8, 9 and co-funded by the European Social Fund – ESF and the Greek State. Metal analysis performed at the Northwestern University Quantitative Bio-element Imaging Center was generously supported by the NASA Ames Research Center Grant NNA04CC36G. MGK would like to acknowledge the grant NSF DMR-1708254. Publisher Copyright: {\textcopyright} The Royal Society of Chemistry.",

year = "2018",

doi = "10.1039/c8ta07901c",

language = "English (US)",

volume = "6",

pages = "20813--20821",

journal = "Journal of Materials Chemistry A",

issn = "2050-7488",

publisher = "Royal Society of Chemistry",

number = "42",

}

Rapti, S, Diamantis, SA, Dafnomili, A, Pournara, A, Skliri, E, Armatas, GS, Tsipis, AC, Spanopoulos, I, Malliakas, CD , Kanatzidis, MG, Plakatouras, JC, Noli, F, Lazarides, T & Manos, MJ 2018, 'Exceptional TcO₄ ⁻ sorption capacity and highly efficient ReO₄ ⁻ luminescence sensing by Zr⁴⁺ MOFs', Journal of Materials Chemistry A, vol. 6, no. 42, pp. 20813-20821. https://doi.org/10.1039/c8ta07901c

TY - JOUR

T1 - Exceptional TcO4 − sorption capacity and highly efficient ReO4 − luminescence sensing by Zr4+ MOFs

AU - Rapti, Sofia

AU - Diamantis, Stavros A.

AU - Dafnomili, Argyro

AU - Pournara, Anastasia

AU - Skliri, Euaggelia

AU - Armatas, Gerasimos S.

AU - Tsipis, Athanassios C.

AU - Spanopoulos, Ioannis

AU - Malliakas, Christos D.

AU - Kanatzidis, Mercouri G.

AU - Plakatouras, John C.

AU - Noli, Fotini

AU - Lazarides, Theodore

AU - Manos, Manolis J.

N1 - Funding Information: The powder X-ray diffraction and thermal analysis units of the Network of Research Supporting Laboratories at the University of Ioannina are acknowledged. The post-doctoral research of Dr A. Pournara was implemented with IKY scholarship, funded by the Act “Supporting Post-Academic Researchers” from the resources of the NF “Human Resources Development, Education and Lifelong Learning” with Priority Axes 6, 8, 9 and co-funded by the European Social Fund – ESF and the Greek State. Metal analysis performed at the Northwestern University Quantitative Bio-element Imaging Center was generously supported by the NASA Ames Research Center Grant NNA04CC36G. MGK would like to acknowledge the grant NSF DMR-1708254. Publisher Copyright: © The Royal Society of Chemistry.

PY - 2018

Y1 - 2018

N2 - The sorption properties of [Zr6O4(OH)4(NH3 +-BDC)6]Cl6·xH2O (MOR-1) and H16[Zr6O16(H2PATP)4]Cl8·xH2O (MOR-2) towards ReO4 − and TcO4 − were studied in detail. Both MOR-1 and MOR-2 are very effective sorbents for ReO4 − and TcO4 − anions, with MOR-2 showing the highest sorption capacity (up to 4.1 ± 0.4 mmol g−1) among the known metal organic materials. Importantly, the exceptional sorption capacity of MOR-2 is retained even under conditions simulating acidic nuclear waste. In addition, MOR-1 and MOR-2 exhibit selective luminescence ReO4 − sensing properties, demonstrated for the first time for MOF materials.

AB - The sorption properties of [Zr6O4(OH)4(NH3 +-BDC)6]Cl6·xH2O (MOR-1) and H16[Zr6O16(H2PATP)4]Cl8·xH2O (MOR-2) towards ReO4 − and TcO4 − were studied in detail. Both MOR-1 and MOR-2 are very effective sorbents for ReO4 − and TcO4 − anions, with MOR-2 showing the highest sorption capacity (up to 4.1 ± 0.4 mmol g−1) among the known metal organic materials. Importantly, the exceptional sorption capacity of MOR-2 is retained even under conditions simulating acidic nuclear waste. In addition, MOR-1 and MOR-2 exhibit selective luminescence ReO4 − sensing properties, demonstrated for the first time for MOF materials.

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U2 - 10.1039/c8ta07901c

DO - 10.1039/c8ta07901c

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VL - 6

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JO - Journal of Materials Chemistry A

JF - Journal of Materials Chemistry A

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