Excimer fluorescence from phenanthrene-9-carboxylate derivatives

Frederick D Lewis*, Eric L. Burch

*Corresponding author for this work

Research output: Contribution to journalArticlepeer-review

12 Scopus citations

Abstract

Phenanthrene and most of its known derivatives do not form stable, fluorescent excimers. Moderately intense, long-lived excimer fluorescence has been observed for lactone and lactam derivatives of phenanthrene. The solvatochromic shift of this excimer fluorescence is similar to that previously reported for the pyrene excimer. Stabilization of the excimer is attributed to the increased polarizability of phenanthrene by a coplanar carbonyl substituent. Excimer formation is not observed for a coplanar cyano substituent or an orthogonal carbonyl substituent.

Original languageEnglish (US)
Pages (from-to)19-23
Number of pages5
JournalJournal of Photochemistry and Photobiology A: Chemistry
Volume96
Issue number1-3
DOIs
StatePublished - May 31 1996

Keywords

  • Excimer fluorescence
  • Phenanthrene-9-carboxylate derivatives
  • Solvatochromic shift

ASJC Scopus subject areas

  • Chemistry(all)
  • Chemical Engineering(all)
  • Physics and Astronomy(all)

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