Extended materials based on the [Mo6Cl8]4+ building block bridged by 4,4′-bipyridine

R. L. Bain; D. F. Shriver; Donald E. Ellis

doi:10.1016/S0020-1693(01)00631-4

Extended materials based on the [Mo₆Cl₈]⁴⁺ building block bridged by 4,4′-bipyridine

R. L. Bain, D. F. Shriver, Donald E. Ellis

Physics and Astronomy

Research output: Contribution to journal › Article › peer-review

34 Scopus citations

Abstract

Octahedral molybdenum clusters containing labile SO₃CF₃^- ligands attached to the vertices of the octahedron were allowed to react with the linear bidentate 4,4′-bipyridine to produce microporous xerogels that exhibit size selective ion exchange.

Original language	English (US)
Pages (from-to)	171-174
Number of pages	4
Journal	Inorganica Chimica Acta
Volume	325
Issue number	1-2
DOIs	https://doi.org/10.1016/S0020-1693(01)00631-4
State	Published - Dec 3 2001

Keywords

Bipyridine
Microporous xerogels
Molybdenum clusters
SOCF ligands

ASJC Scopus subject areas

Physical and Theoretical Chemistry
Inorganic Chemistry
Materials Chemistry

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10.1016/S0020-1693(01)00631-4

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title = "Extended materials based on the [Mo6Cl8]4+ building block bridged by 4,4′-bipyridine",

abstract = "Octahedral molybdenum clusters containing labile SO3CF3- ligands attached to the vertices of the octahedron were allowed to react with the linear bidentate 4,4′-bipyridine to produce microporous xerogels that exhibit size selective ion exchange.",

keywords = "Bipyridine, Microporous xerogels, Molybdenum clusters, SOCF ligands",

author = "Bain, {R. L.} and Shriver, {D. F.} and Ellis, {Donald E.}",

year = "2001",

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AU - Bain, R. L.

AU - Shriver, D. F.

AU - Ellis, Donald E.

PY - 2001/12/3

Y1 - 2001/12/3

N2 - Octahedral molybdenum clusters containing labile SO3CF3- ligands attached to the vertices of the octahedron were allowed to react with the linear bidentate 4,4′-bipyridine to produce microporous xerogels that exhibit size selective ion exchange.

AB - Octahedral molybdenum clusters containing labile SO3CF3- ligands attached to the vertices of the octahedron were allowed to react with the linear bidentate 4,4′-bipyridine to produce microporous xerogels that exhibit size selective ion exchange.

KW - Bipyridine

KW - Microporous xerogels

KW - Molybdenum clusters

KW - SOCF ligands

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