Extended materials based on the [Mo6Cl8]4+ building block bridged by 4,4′-bipyridine

R. L. Bain; D. F. Shriver; Donald E. Ellis

doi:10.1016/S0020-1693(01)00631-4

Extended materials based on the [Mo₆Cl₈]⁴⁺ building block bridged by 4,4′-bipyridine

R. L. Bain, D. F. Shriver, Donald E. Ellis

Physics and Astronomy

Research output: Contribution to journal › Article › peer-review

34 Scopus citations

Abstract

Octahedral molybdenum clusters containing labile SO₃CF₃^- ligands attached to the vertices of the octahedron were allowed to react with the linear bidentate 4,4′-bipyridine to produce microporous xerogels that exhibit size selective ion exchange.

Original language	English (US)
Pages (from-to)	171-174
Number of pages	4
Journal	Inorganica Chimica Acta
Volume	325
Issue number	1-2
DOIs	https://doi.org/10.1016/S0020-1693(01)00631-4
State	Published - Dec 3 2001

Funding

This research was supported by the National Science Foundation award number (9014662) and the MRSEC program of the NSF (DMR 0076097) at the Materials Research Center of Northwestern University.

Keywords

Bipyridine
Microporous xerogels
Molybdenum clusters
SOCF ligands

ASJC Scopus subject areas

Physical and Theoretical Chemistry
Inorganic Chemistry
Materials Chemistry

Access to Document

10.1016/S0020-1693(01)00631-4

Cite this

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title = "Extended materials based on the [Mo6Cl8]4+ building block bridged by 4,4′-bipyridine",

abstract = "Octahedral molybdenum clusters containing labile SO3CF3- ligands attached to the vertices of the octahedron were allowed to react with the linear bidentate 4,4′-bipyridine to produce microporous xerogels that exhibit size selective ion exchange.",

keywords = "Bipyridine, Microporous xerogels, Molybdenum clusters, SOCF ligands",

author = "Bain, {R. L.} and Shriver, {D. F.} and Ellis, {Donald E.}",

note = "Funding Information: This research was supported by the National Science Foundation award number (9014662) and the MRSEC program of the NSF (DMR 0076097) at the Materials Research Center of Northwestern University. ",

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doi = "10.1016/S0020-1693(01)00631-4",

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journal = "Inorganica Chimica Acta",

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AU - Bain, R. L.

AU - Shriver, D. F.

AU - Ellis, Donald E.

N1 - Funding Information: This research was supported by the National Science Foundation award number (9014662) and the MRSEC program of the NSF (DMR 0076097) at the Materials Research Center of Northwestern University.

PY - 2001/12/3

Y1 - 2001/12/3

N2 - Octahedral molybdenum clusters containing labile SO3CF3- ligands attached to the vertices of the octahedron were allowed to react with the linear bidentate 4,4′-bipyridine to produce microporous xerogels that exhibit size selective ion exchange.

AB - Octahedral molybdenum clusters containing labile SO3CF3- ligands attached to the vertices of the octahedron were allowed to react with the linear bidentate 4,4′-bipyridine to produce microporous xerogels that exhibit size selective ion exchange.

KW - Bipyridine

KW - Microporous xerogels

KW - Molybdenum clusters

KW - SOCF ligands

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