Fabrication of transparent-conducting-oxide-coated inverse opals as mesostructured architectures for electrocatalysis applications: A case study with NiO

Vennesa O. Williams; Erica J. Demarco; Michael J. Katz; Joseph A. Libera; Shannon C. Riha; Dong Wook Kim; Jason R. Avila; Alex B.F. Martinson; Jeffrey W. Elam; Michael J. Pellin; Omar k Farha; Joseph T Hupp

doi:10.1021/am501910n

Fabrication of transparent-conducting-oxide-coated inverse opals as mesostructured architectures for electrocatalysis applications: A case study with NiO

Vennesa O. Williams, Erica J. Demarco, Michael J. Katz, Joseph A. Libera, Shannon C. Riha, Dong Wook Kim, Jason R. Avila, Alex B.F. Martinson, Jeffrey W. Elam, Michael J. Pellin, Omar k Farha^*, Joseph T Hupp

^*Corresponding author for this work

Chemistry

Research output: Contribution to journal › Article › peer-review

27 Scopus citations

Abstract

Highly ordered, and conductive inverse opal arrays were made with silica and subsequently coated with tin-doped indium oxide (ITO) via atomic layer deposition (ALD). We demonstrate the utility of the resulting mesostructured electrodes by further coating them with nickel oxide via ALD. The NiO-coated arrays are capable of efficiently electrochemically evolving oxygen from water. These modular, crack-free, transparent, high surface area, and conducting structures show promise for many applications including electrocatalysis, photocatalysis, and dye-sensitized solar cells.

Original language	English (US)
Pages (from-to)	12290-12294
Number of pages	5
Journal	ACS Applied Materials and Interfaces
Volume	6
Issue number	15
DOIs	https://doi.org/10.1021/am501910n
State	Published - Aug 13 2014

Keywords

atomic-layer deposition
catalysis
electrochemistry
inverse opals
nickel oxide
water oxidation

ASJC Scopus subject areas

General Materials Science

UN SDGs

This output contributes to the following UN Sustainable Development Goals (SDGs)

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10.1021/am501910n

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Williams, V. O., Demarco, E. J., Katz, M. J., Libera, J. A., Riha, S. C., Kim, D. W., Avila, J. R., Martinson, A. B. F., Elam, J. W., Pellin, M. J., Farha, O. K., & Hupp, J. T. (2014). Fabrication of transparent-conducting-oxide-coated inverse opals as mesostructured architectures for electrocatalysis applications: A case study with NiO. ACS Applied Materials and Interfaces, 6(15), 12290-12294. https://doi.org/10.1021/am501910n

@article{747a5b64241148f09a6fec7e2a627b17,

title = "Fabrication of transparent-conducting-oxide-coated inverse opals as mesostructured architectures for electrocatalysis applications: A case study with NiO",

abstract = "Highly ordered, and conductive inverse opal arrays were made with silica and subsequently coated with tin-doped indium oxide (ITO) via atomic layer deposition (ALD). We demonstrate the utility of the resulting mesostructured electrodes by further coating them with nickel oxide via ALD. The NiO-coated arrays are capable of efficiently electrochemically evolving oxygen from water. These modular, crack-free, transparent, high surface area, and conducting structures show promise for many applications including electrocatalysis, photocatalysis, and dye-sensitized solar cells.",

keywords = "atomic-layer deposition, catalysis, electrochemistry, inverse opals, nickel oxide, water oxidation",

author = "Williams, {Vennesa O.} and Demarco, {Erica J.} and Katz, {Michael J.} and Libera, {Joseph A.} and Riha, {Shannon C.} and Kim, {Dong Wook} and Avila, {Jason R.} and Martinson, {Alex B.F.} and Elam, {Jeffrey W.} and Pellin, {Michael J.} and Farha, {Omar k} and Hupp, {Joseph T}",

year = "2014",

month = aug,

day = "13",

doi = "10.1021/am501910n",

language = "English (US)",

volume = "6",

pages = "12290--12294",

journal = "ACS Applied Materials and Interfaces",

issn = "1944-8244",

publisher = "American Chemical Society",

number = "15",

}

Williams, VO, Demarco, EJ, Katz, MJ, Libera, JA, Riha, SC, Kim, DW, Avila, JR, Martinson, ABF, Elam, JW, Pellin, MJ, Farha, OK & Hupp, JT 2014, 'Fabrication of transparent-conducting-oxide-coated inverse opals as mesostructured architectures for electrocatalysis applications: A case study with NiO', ACS Applied Materials and Interfaces, vol. 6, no. 15, pp. 12290-12294. https://doi.org/10.1021/am501910n

Fabrication of transparent-conducting-oxide-coated inverse opals as mesostructured architectures for electrocatalysis applications: A case study with NiO. / Williams, Vennesa O.; Demarco, Erica J.; Katz, Michael J. et al.
In: ACS Applied Materials and Interfaces, Vol. 6, No. 15, 13.08.2014, p. 12290-12294.

Research output: Contribution to journal › Article › peer-review

TY - JOUR

T1 - Fabrication of transparent-conducting-oxide-coated inverse opals as mesostructured architectures for electrocatalysis applications

T2 - A case study with NiO

AU - Williams, Vennesa O.

AU - Demarco, Erica J.

AU - Katz, Michael J.

AU - Libera, Joseph A.

AU - Riha, Shannon C.

AU - Kim, Dong Wook

AU - Avila, Jason R.

AU - Martinson, Alex B.F.

AU - Elam, Jeffrey W.

AU - Pellin, Michael J.

AU - Farha, Omar k

AU - Hupp, Joseph T

PY - 2014/8/13

Y1 - 2014/8/13

N2 - Highly ordered, and conductive inverse opal arrays were made with silica and subsequently coated with tin-doped indium oxide (ITO) via atomic layer deposition (ALD). We demonstrate the utility of the resulting mesostructured electrodes by further coating them with nickel oxide via ALD. The NiO-coated arrays are capable of efficiently electrochemically evolving oxygen from water. These modular, crack-free, transparent, high surface area, and conducting structures show promise for many applications including electrocatalysis, photocatalysis, and dye-sensitized solar cells.

AB - Highly ordered, and conductive inverse opal arrays were made with silica and subsequently coated with tin-doped indium oxide (ITO) via atomic layer deposition (ALD). We demonstrate the utility of the resulting mesostructured electrodes by further coating them with nickel oxide via ALD. The NiO-coated arrays are capable of efficiently electrochemically evolving oxygen from water. These modular, crack-free, transparent, high surface area, and conducting structures show promise for many applications including electrocatalysis, photocatalysis, and dye-sensitized solar cells.

KW - atomic-layer deposition

KW - catalysis

KW - electrochemistry

KW - inverse opals

KW - nickel oxide

KW - water oxidation

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U2 - 10.1021/am501910n

DO - 10.1021/am501910n

M3 - Article

C2 - 25033088

AN - SCOPUS:84906252962

SN - 1944-8244

VL - 6

SP - 12290

EP - 12294

JO - ACS Applied Materials and Interfaces

JF - ACS Applied Materials and Interfaces

IS - 15

ER -

Fabrication of transparent-conducting-oxide-coated inverse opals as mesostructured architectures for electrocatalysis applications: A case study with NiO

Abstract

Keywords

ASJC Scopus subject areas

UN SDGs

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