Abstract
Structural analyses for the title compounds, (OC-6-32)-tricarbonylchlorobis(pyridine-N)rhenium(I), [ReCl-(C5H5N)2(CO)3], and (OC-6-32)-tricarbonylchlorobis-(4,4′-bipyridine-N)rhenium(I), [ReCl(C10H8N2)2(CO)3], show that both complexes have the expected facoctahedral geometry. The bipyridine complex has local C2 symmetry, with the rotation axis bisecting the N - Re - N′ and OC - Re - CO angles. In contrast with closely related tetrameric assemblies which crystallize as porous channel-containing structures, the title compounds form dense crystals which are packed in a herring-bone fashion.
| Original language | English (US) |
|---|---|
| Pages (from-to) | 1596-1600 |
| Number of pages | 5 |
| Journal | Acta Crystallographica Section C: Crystal Structure Communications |
| Volume | 54 |
| Issue number | 11 |
| DOIs | |
| State | Published - Nov 15 1998 |
ASJC Scopus subject areas
- General Biochemistry, Genetics and Molecular Biology
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CCDC 130538: Experimental Crystal Structure Determination
Bélanger, S. (Contributor), Hupp, J. T. (Creator) & Stern, C. L. (Creator), Cambridge Crystallographic Data Centre, 1999
DOI: 10.5517/cc4ctx6, http://www.ccdc.cam.ac.uk/services/structure_request?id=doi:10.5517/cc4ctx6&sid=DataCite
Dataset
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CCDC 130539: Experimental Crystal Structure Determination
Bélanger, S. (Contributor), Hupp, J. T. (Creator) & Stern, C. L. (Creator), Cambridge Crystallographic Data Centre, 1999
DOI: 10.5517/cc4cty7, http://www.ccdc.cam.ac.uk/services/structure_request?id=doi:10.5517/cc4cty7&sid=DataCite
Dataset