Abstract
Facile syntheses of [K([2.2.2]-cryptand)]3Ag(Se2C2(CN)2)(Se6)] (1) and [K([2.2.2]-cryptand)]2-[Ni(Se2C2(CN)2)2] (2) are achieved through reaction of polyselenides with KNH2, [2.2.2]-cryptand, and AgBF4 or Ni(dppp)Cl2 in acetonitrile. The syntheses of 2 and Ni(dppp)(Se2C2(CN)2) (3) may be achieved by reaction of 1 with NiCl2 or Ni(dppp)Cl2 in dmf. These compounds represent the first easily prepared metal-maleonitrilediselenolate derivatives.
Original language | English (US) |
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Pages (from-to) | 1046-1048 |
Number of pages | 3 |
Journal | Inorganic Chemistry |
Volume | 39 |
Issue number | 5 |
DOIs | |
State | Published - Mar 6 2000 |
ASJC Scopus subject areas
- Physical and Theoretical Chemistry
- Inorganic Chemistry