Failure of cyclopropyl bromide to add oxidatively to ZrCp2(PMePh2)2: Reaction of C3H4Br with ZrCp2(PMePh2)2 in toluene to afford ZrBr(CH2Ph)Cp2

Clayton R. Randall, Michael E. Silver, James A. Ibers*

*Corresponding author for this work

Research output: Contribution to journalArticlepeer-review

5 Scopus citations

Abstract

Reaction of ZrCp2(PMePh2)2 (Cp=η5-cyclopentadtenyl) with cyclopropyl bromtde in toluene, rather than affording ZrBr(C3H5)Cp2 as expected, affords ZrBr(CH2Ph)Cp2 with the elimination of cyclopropane.

Original languageEnglish (US)
Pages (from-to)39-42
Number of pages4
JournalInorganica Chimica Acta
Volume128
Issue number1
DOIs
StatePublished - Apr 1 1987

ASJC Scopus subject areas

  • Physical and Theoretical Chemistry
  • Inorganic Chemistry
  • Materials Chemistry

Fingerprint Dive into the research topics of 'Failure of cyclopropyl bromide to add oxidatively to ZrCp<sub>2</sub>(PMePh<sub>2</sub>)<sub>2</sub>: Reaction of C<sub>3</sub>H<sub>4</sub>Br with ZrCp<sub>2</sub>(PMePh<sub>2</sub>)<sub>2</sub> in toluene to afford ZrBr(CH<sub>2</sub>Ph)Cp<sub>2</sub>'. Together they form a unique fingerprint.

Cite this