Failure of cyclopropyl bromide to add oxidatively to ZrCp2(PMePh2)2: Reaction of C3H4Br with ZrCp2(PMePh2)2 in toluene to afford ZrBr(CH2Ph)Cp2

Clayton R. Randall; Michael E. Silver; James A. Ibers

doi:10.1016/S0020-1693(00)84692-7

Failure of cyclopropyl bromide to add oxidatively to ZrCp₂(PMePh₂)₂: Reaction of C₃H₄Br with ZrCp₂(PMePh₂)₂ in toluene to afford ZrBr(CH₂Ph)Cp₂

Clayton R. Randall, Michael E. Silver, James A. Ibers^*

^*Corresponding author for this work

Chemistry

Research output: Contribution to journal › Article › peer-review

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Abstract

Reaction of ZrCp₂(PMePh₂)₂ (Cp=η⁵-cyclopentadtenyl) with cyclopropyl bromtde in toluene, rather than affording ZrBr(C₃H₅)Cp₂ as expected, affords ZrBr(CH₂Ph)Cp₂ with the elimination of cyclopropane.

Original language	English (US)
Pages (from-to)	39-42
Number of pages	4
Journal	Inorganica Chimica Acta
Volume	128
Issue number	1
DOIs	https://doi.org/10.1016/S0020-1693(00)84692-7
State	Published - Apr 1 1987

ASJC Scopus subject areas

Physical and Theoretical Chemistry
Inorganic Chemistry
Materials Chemistry

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@article{6c50e3c3d6ea4a2b85a20dbb216b5f70,

title = "Failure of cyclopropyl bromide to add oxidatively to ZrCp2(PMePh2)2: Reaction of C3H4Br with ZrCp2(PMePh2)2 in toluene to afford ZrBr(CH2Ph)Cp2",

abstract = "Reaction of ZrCp2(PMePh2)2 (Cp=η5-cyclopentadtenyl) with cyclopropyl bromtde in toluene, rather than affording ZrBr(C3H5)Cp2 as expected, affords ZrBr(CH2Ph)Cp2 with the elimination of cyclopropane.",

author = "Randall, {Clayton R.} and Silver, {Michael E.} and Ibers, {James A.}",

note = "Funding Information: This researchw as supported by the U.S. National ScienceF oundation (Grant CHE83-08076).",

year = "1987",

month = apr,

day = "1",

doi = "10.1016/S0020-1693(00)84692-7",

language = "English (US)",

volume = "128",

pages = "39--42",

journal = "Inorganica Chimica Acta",

issn = "0020-1693",

publisher = "Elsevier BV",

number = "1",

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TY - JOUR

T1 - Failure of cyclopropyl bromide to add oxidatively to ZrCp2(PMePh2)2

T2 - Reaction of C3H4Br with ZrCp2(PMePh2)2 in toluene to afford ZrBr(CH2Ph)Cp2

AU - Randall, Clayton R.

AU - Silver, Michael E.

AU - Ibers, James A.

N1 - Funding Information: This researchw as supported by the U.S. National ScienceF oundation (Grant CHE83-08076).

PY - 1987/4/1

Y1 - 1987/4/1

N2 - Reaction of ZrCp2(PMePh2)2 (Cp=η5-cyclopentadtenyl) with cyclopropyl bromtde in toluene, rather than affording ZrBr(C3H5)Cp2 as expected, affords ZrBr(CH2Ph)Cp2 with the elimination of cyclopropane.

AB - Reaction of ZrCp2(PMePh2)2 (Cp=η5-cyclopentadtenyl) with cyclopropyl bromtde in toluene, rather than affording ZrBr(C3H5)Cp2 as expected, affords ZrBr(CH2Ph)Cp2 with the elimination of cyclopropane.

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U2 - 10.1016/S0020-1693(00)84692-7

DO - 10.1016/S0020-1693(00)84692-7

M3 - Article

AN - SCOPUS:33645374474

SN - 0020-1693

VL - 128

SP - 39

EP - 42

JO - Inorganica Chimica Acta

JF - Inorganica Chimica Acta

IS - 1

ER -

Failure of cyclopropyl bromide to add oxidatively to ZrCp₂(PMePh₂)₂: Reaction of C₃H₄Br with ZrCp₂(PMePh₂)₂ in toluene to afford ZrBr(CH₂Ph)Cp₂

Abstract

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