Ferrocene and maleimide-functionalized disulfide scaffolds for self-assembled monolayers on gold

Paul A. Bertin; Michael J. Ahrens; Kinjal Bhavsar; Dimitra Georganopoulou; Markus Wunder; Gary F. Blackburn; Thomas J. Meade

doi:10.1021/ol101180r

Ferrocene and maleimide-functionalized disulfide scaffolds for self-assembled monolayers on gold

Paul A. Bertin, Michael J. Ahrens, Kinjal Bhavsar, Dimitra Georganopoulou, Markus Wunder, Gary F. Blackburn, Thomas J. Meade

Chemistry

Research output: Contribution to journal › Article › peer-review

12 Scopus citations

Abstract

(Equation Presented). A series of ferrocene-based electroactive molecules (EAMs) containing maleimide and disulfide groups in different asymmetric and branched architectures were designed and synthesized. Stable monolayers of each EAM on gold electrodes were confirmed by cyclic voltammetry. Importantly, these EAMs expand the repertoire of monolayer building blocks amenable to modular biofunctionalization for applications in electrochemical biosensor fabrication.

Original language	English (US)
Pages (from-to)	3372-3375
Number of pages	4
Journal	Organic Letters
Volume	12
Issue number	15
DOIs	https://doi.org/10.1021/ol101180r
State	Published - Aug 6 2010

ASJC Scopus subject areas

Biochemistry
Physical and Theoretical Chemistry
Organic Chemistry

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10.1021/ol101180r

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abstract = "(Equation Presented). A series of ferrocene-based electroactive molecules (EAMs) containing maleimide and disulfide groups in different asymmetric and branched architectures were designed and synthesized. Stable monolayers of each EAM on gold electrodes were confirmed by cyclic voltammetry. Importantly, these EAMs expand the repertoire of monolayer building blocks amenable to modular biofunctionalization for applications in electrochemical biosensor fabrication.",

author = "Bertin, {Paul A.} and Ahrens, {Michael J.} and Kinjal Bhavsar and Dimitra Georganopoulou and Markus Wunder and Blackburn, {Gary F.} and Meade, {Thomas J.}",

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T1 - Ferrocene and maleimide-functionalized disulfide scaffolds for self-assembled monolayers on gold

AU - Bertin, Paul A.

AU - Ahrens, Michael J.

AU - Bhavsar, Kinjal

AU - Georganopoulou, Dimitra

AU - Wunder, Markus

AU - Blackburn, Gary F.

AU - Meade, Thomas J.

PY - 2010/8/6

Y1 - 2010/8/6

N2 - (Equation Presented). A series of ferrocene-based electroactive molecules (EAMs) containing maleimide and disulfide groups in different asymmetric and branched architectures were designed and synthesized. Stable monolayers of each EAM on gold electrodes were confirmed by cyclic voltammetry. Importantly, these EAMs expand the repertoire of monolayer building blocks amenable to modular biofunctionalization for applications in electrochemical biosensor fabrication.

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Ferrocene and maleimide-functionalized disulfide scaffolds for self-assembled monolayers on gold

Abstract

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