[Fe3Cu(SPri)6Cl3]2-: A novel mixed-metal thiolate complex with a 'truncated' adamantane-like structure

Hans Oscar Stephan; Gerald Henkel; Mercouri G. Kanatzidis

doi:10.1039/a606962b

[Fe₃Cu(SPrⁱ)₆Cl₃]^2-: A novel mixed-metal thiolate complex with a 'truncated' adamantane-like structure

Hans Oscar Stephan, Gerald Henkel, Mercouri G. Kanatzidis^*

^*Corresponding author for this work

Chemistry

Research output: Contribution to journal › Article › peer-review

7 Scopus citations

Abstract

Reaction of [Fe₂(SPrⁱ)₆]^2- with FeCl₂ and CuCl in a 1:1:1 molar ratio in hot tetrahydrofuran gives the complex anion [Fe₃Cu(SPrⁱ)₆Cl₃]^2- which contains a Fe₃Cu pyramidal core; the structure, magnetic properties and the solution ¹H NMR spectrum are reported.

Original language	English (US)
Pages (from-to)	67-68
Number of pages	2
Journal	Chemical Communications
Issue number	1
DOIs	https://doi.org/10.1039/a606962b
State	Published - Jan 1 1997

ASJC Scopus subject areas

Catalysis
Electronic, Optical and Magnetic Materials
Ceramics and Composites
Chemistry(all)
Surfaces, Coatings and Films
Metals and Alloys
Materials Chemistry

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title = "[Fe3Cu(SPri)6Cl3]2-: A novel mixed-metal thiolate complex with a 'truncated' adamantane-like structure",

abstract = "Reaction of [Fe2(SPri)6]2- with FeCl2 and CuCl in a 1:1:1 molar ratio in hot tetrahydrofuran gives the complex anion [Fe3Cu(SPri)6Cl3]2- which contains a Fe3Cu pyramidal core; the structure, magnetic properties and the solution 1H NMR spectrum are reported.",

author = "Stephan, {Hans Oscar} and Gerald Henkel and Kanatzidis, {Mercouri G.}",

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AU - Stephan, Hans Oscar

AU - Henkel, Gerald

AU - Kanatzidis, Mercouri G.

PY - 1997/1/1

Y1 - 1997/1/1

N2 - Reaction of [Fe2(SPri)6]2- with FeCl2 and CuCl in a 1:1:1 molar ratio in hot tetrahydrofuran gives the complex anion [Fe3Cu(SPri)6Cl3]2- which contains a Fe3Cu pyramidal core; the structure, magnetic properties and the solution 1H NMR spectrum are reported.

AB - Reaction of [Fe2(SPri)6]2- with FeCl2 and CuCl in a 1:1:1 molar ratio in hot tetrahydrofuran gives the complex anion [Fe3Cu(SPri)6Cl3]2- which contains a Fe3Cu pyramidal core; the structure, magnetic properties and the solution 1H NMR spectrum are reported.

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[Fe₃Cu(SPrⁱ)₆Cl₃]^2-: A novel mixed-metal thiolate complex with a 'truncated' adamantane-like structure

Abstract

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