Flexible redox-active binuclear macrocycles formed via the weak-link approach and novel hemilabile ligands with N,N,N′,N′-tetramethyl-1,4-phenylenediamine units

X. Liu; A. H. Eisenberg; C. L. Stern; C. A. Mirkin

doi:10.1021/ic010393i

Flexible redox-active binuclear macrocycles formed via the weak-link approach and novel hemilabile ligands with N,N,N′,N′-tetramethyl-1,4-phenylenediamine units

X. Liu, A. H. Eisenberg, C. L. Stern, C. A. Mirkin^*

^*Corresponding author for this work

Robert H. Lurie Comprehensive Cancer Center

Research output: Contribution to journal › Article › peer-review

37 Scopus citations

Abstract

A method that utilizes the "weak-link synthetic approach" to binuclear macrocycles and a hemilabile ligand derived from Wurster's reagent (N,N,N′,N′-tetramethyl-1,4-phenylenediamine (TMPD)) to prepare a new class of redox-active binuclear macrocycles is reported. This novel system provides a new platform for preparing a diverse collection of redox-active supramolecular structures with tailorable architectural parameters.

Original language	English (US)
Pages (from-to)	2940-2941
Number of pages	2
Journal	Inorganic chemistry
Volume	40
Issue number	13
DOIs	https://doi.org/10.1021/ic010393i
State	Published - Jun 18 2001

ASJC Scopus subject areas

Inorganic Chemistry
Physical and Theoretical Chemistry

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10.1021/ic010393i

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year = "2001",

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journal = "Inorganic chemistry",

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AU - Liu, X.

AU - Eisenberg, A. H.

AU - Stern, C. L.

AU - Mirkin, C. A.

PY - 2001/6/18

Y1 - 2001/6/18

N2 - A method that utilizes the "weak-link synthetic approach" to binuclear macrocycles and a hemilabile ligand derived from Wurster's reagent (N,N,N′,N′-tetramethyl-1,4-phenylenediamine (TMPD)) to prepare a new class of redox-active binuclear macrocycles is reported. This novel system provides a new platform for preparing a diverse collection of redox-active supramolecular structures with tailorable architectural parameters.

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ER -

Flexible redox-active binuclear macrocycles formed via the weak-link approach and novel hemilabile ligands with N,N,N′,N′-tetramethyl-1,4-phenylenediamine units

Abstract

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CCDC 187511: Experimental Crystal Structure Determination

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Flexible redox-active binuclear macrocycles formed via the weak-link approach and novel hemilabile ligands with N,N,N′,N′-tetramethyl-1,4-phenylenediamine units

Abstract

ASJC Scopus subject areas

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Fingerprint

Datasets

CCDC 187511: Experimental Crystal Structure Determination

Cite this