Formation of new acid sites in dilute oxide solid solutions: A predictive model

Harold H. Kung*

*Corresponding author for this work

Research output: Contribution to journalArticlepeer-review

84 Scopus citations

Abstract

A predictive model for the formation of new acid sites in a dilute solid solution of two component oxides is being developed by examining the electrostatic potential at the substituting cation site and the changes in the matrix necessary to balance the stoichiometry. When the prediction was used to compare with experimental results, the satisfactory comparison suggests that the electrostatic potential and the balance of stoichiometry are the two dominant factors in new acid site formation. The implications of this are discussed.

Original languageEnglish (US)
Pages (from-to)191-196
Number of pages6
JournalJournal of Solid State Chemistry
Volume52
Issue number2
DOIs
StatePublished - Apr 1984

ASJC Scopus subject areas

  • Electronic, Optical and Magnetic Materials
  • Ceramics and Composites
  • Condensed Matter Physics
  • Physical and Theoretical Chemistry
  • Inorganic Chemistry
  • Materials Chemistry

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