TY - JOUR
T1 - Formation of Thioarsenide from the Reductive Coupling of Dithionite and Arsenite under Hydrothermal Conditions. Synthesis of (Ph4 P)[Fe2 (AsS)(CO)6]
AU - Das, Birinchi K.
AU - Kanatzidis, Mercouri G.
PY - 1995/12/1
Y1 - 1995/12/1
N2 - The iron carbonyl cluster compound (Ph4 P)[Fe2 (AsS)(CO)6] (1) containing the thioarsenate ligand AsS3− has been hydrothermally synthesized at 130 °C from a mixture of Fe3(CO)12, NaAsO2, Na2 S2 O4, and Ph4 PBr in the 1:3:6:3 molar ratio. This air-stable, orange yellow compound crystallizes in the triclinic space group P-1 (No. 2) with a = 11409(2) Å, b = 12.273(3) Å, c = 12.277(3) Å, α = 108.17(2)°, β = 102.05(2)°, γ = 106.60(2)°, V = 1479(1) Å3, and Z = 2. The [Fe2 (AsS)(CO)6]− anion in 1 is isostructural and isoelectronic to Fe2 (S2)(CO)6.
AB - The iron carbonyl cluster compound (Ph4 P)[Fe2 (AsS)(CO)6] (1) containing the thioarsenate ligand AsS3− has been hydrothermally synthesized at 130 °C from a mixture of Fe3(CO)12, NaAsO2, Na2 S2 O4, and Ph4 PBr in the 1:3:6:3 molar ratio. This air-stable, orange yellow compound crystallizes in the triclinic space group P-1 (No. 2) with a = 11409(2) Å, b = 12.273(3) Å, c = 12.277(3) Å, α = 108.17(2)°, β = 102.05(2)°, γ = 106.60(2)°, V = 1479(1) Å3, and Z = 2. The [Fe2 (AsS)(CO)6]− anion in 1 is isostructural and isoelectronic to Fe2 (S2)(CO)6.
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U2 - 10.1021/ic00130a016
DO - 10.1021/ic00130a016
M3 - Article
AN - SCOPUS:0000123507
SN - 0020-1669
VL - 34
SP - 6505
EP - 6508
JO - Inorganic chemistry
JF - Inorganic chemistry
IS - 26
ER -