TY - JOUR
T1 - Frontal analysis of product peaks from gas chromatographic reactors. Dicyclopentadiene and di-tert.-butyl peroxide decomposition
AU - Patton, James E.
AU - Kung, Harold
AU - Langer, Stanley H.
N1 - Funding Information:
We thank the Petroleum Research Fund, administered by the American Chemical Society, and the American Oil Company for support of this work.
PY - 1975/1/29
Y1 - 1975/1/29
N2 - The chromatographic curve resulting from pulse injection of a reactant into a chromatographic column may contain significant information about products. Under some conditions, the elution volume or time at one-half the step height of the product curve approximates the characteristic elution volume, or time, of product material. This may even be true when reactants give several products. Such information may be used for product identification and obtaining solution thermodynamic data.
AB - The chromatographic curve resulting from pulse injection of a reactant into a chromatographic column may contain significant information about products. Under some conditions, the elution volume or time at one-half the step height of the product curve approximates the characteristic elution volume, or time, of product material. This may even be true when reactants give several products. Such information may be used for product identification and obtaining solution thermodynamic data.
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U2 - 10.1016/S0021-9673(01)85489-3
DO - 10.1016/S0021-9673(01)85489-3
M3 - Article
AN - SCOPUS:0010619287
SN - 0021-9673
VL - 104
SP - 73
EP - 79
JO - Journal of Chromatography A
JF - Journal of Chromatography A
IS - 1
ER -