Frontal analysis of product peaks from gas chromatographic reactors. Dicyclopentadiene and di-tert.-butyl peroxide decomposition

James E. Patton; Harold Kung; Stanley H. Langer

doi:10.1016/S0021-9673(01)85489-3

Frontal analysis of product peaks from gas chromatographic reactors. Dicyclopentadiene and di-tert.-butyl peroxide decomposition

James E. Patton, Harold Kung, Stanley H. Langer^*

^*Corresponding author for this work

Chemical and Biological Engineering

Research output: Contribution to journal › Article › peer-review

4 Scopus citations

Abstract

The chromatographic curve resulting from pulse injection of a reactant into a chromatographic column may contain significant information about products. Under some conditions, the elution volume or time at one-half the step height of the product curve approximates the characteristic elution volume, or time, of product material. This may even be true when reactants give several products. Such information may be used for product identification and obtaining solution thermodynamic data.

Original language	English (US)
Pages (from-to)	73-79
Number of pages	7
Journal	Journal of Chromatography A
Volume	104
Issue number	1
DOIs	https://doi.org/10.1016/S0021-9673(01)85489-3
State	Published - Jan 29 1975

Funding

We thank the Petroleum Research Fund, administered by the American Chemical Society, and the American Oil Company for support of this work.

ASJC Scopus subject areas

Analytical Chemistry
Biochemistry
Organic Chemistry

Access to Document

10.1016/S0021-9673(01)85489-3

Cite this

@article{bcc6fa8f92ff4f818e9ed99e465de88d,

title = "Frontal analysis of product peaks from gas chromatographic reactors. Dicyclopentadiene and di-tert.-butyl peroxide decomposition",

abstract = "The chromatographic curve resulting from pulse injection of a reactant into a chromatographic column may contain significant information about products. Under some conditions, the elution volume or time at one-half the step height of the product curve approximates the characteristic elution volume, or time, of product material. This may even be true when reactants give several products. Such information may be used for product identification and obtaining solution thermodynamic data.",

author = "Patton, {James E.} and Harold Kung and Langer, {Stanley H.}",

note = "Funding Information: We thank the Petroleum Research Fund, administered by the American Chemical Society, and the American Oil Company for support of this work.",

year = "1975",

month = jan,

day = "29",

doi = "10.1016/S0021-9673(01)85489-3",

language = "English (US)",

volume = "104",

pages = "73--79",

journal = "Journal of Chromatography A",

issn = "0021-9673",

publisher = "Elsevier B.V.",

number = "1",

}

TY - JOUR

T1 - Frontal analysis of product peaks from gas chromatographic reactors. Dicyclopentadiene and di-tert.-butyl peroxide decomposition

AU - Patton, James E.

AU - Kung, Harold

AU - Langer, Stanley H.

N1 - Funding Information: We thank the Petroleum Research Fund, administered by the American Chemical Society, and the American Oil Company for support of this work.

PY - 1975/1/29

Y1 - 1975/1/29

N2 - The chromatographic curve resulting from pulse injection of a reactant into a chromatographic column may contain significant information about products. Under some conditions, the elution volume or time at one-half the step height of the product curve approximates the characteristic elution volume, or time, of product material. This may even be true when reactants give several products. Such information may be used for product identification and obtaining solution thermodynamic data.

AB - The chromatographic curve resulting from pulse injection of a reactant into a chromatographic column may contain significant information about products. Under some conditions, the elution volume or time at one-half the step height of the product curve approximates the characteristic elution volume, or time, of product material. This may even be true when reactants give several products. Such information may be used for product identification and obtaining solution thermodynamic data.

UR - http://www.scopus.com/inward/record.url?scp=0010619287&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=0010619287&partnerID=8YFLogxK

U2 - 10.1016/S0021-9673(01)85489-3

DO - 10.1016/S0021-9673(01)85489-3

M3 - Article

AN - SCOPUS:0010619287

SN - 0021-9673

VL - 104

SP - 73

EP - 79

JO - Journal of Chromatography A

JF - Journal of Chromatography A

IS - 1

ER -

Frontal analysis of product peaks from gas chromatographic reactors. Dicyclopentadiene and di-tert.-butyl peroxide decomposition

Abstract

Funding

ASJC Scopus subject areas

Access to Document

Other files and links

Fingerprint

Cite this