Functionalised cyclodextrin-based metal-organic frameworks

K. J. Hartlieb; A. W. Peters; T. C. Wang; P. Deria; O. K. Farha; J. T. Hupp; J. F. Stoddart

doi:10.1039/c7cc03345a

Functionalised cyclodextrin-based metal-organic frameworks

K. J. Hartlieb, A. W. Peters, T. C. Wang, P. Deria, O. K. Farha, J. T. Hupp, J. F. Stoddart

Chemistry

Research output: Contribution to journal › Article › peer-review

43 Scopus citations

Abstract

CD-MOF, an extended framework incorporating the C₈ symmetric cyclic oligosaccharide, γ-cyclodextrin (γ-CD), is based on the coordination of alkali metal cations to alternating α-1,4-linked d-glucopyranosyl units on the primary and secondary faces of the γ-CD tori. Here, we report the synthesis and characterisation of an amino-functionalised CD-MOF that is isostructural with pristine CD-MOF and adsorbs CO₂ permanently.

Original language	English (US)
Pages (from-to)	7561-7564
Number of pages	4
Journal	Chemical Communications
Volume	53
Issue number	54
DOIs	https://doi.org/10.1039/c7cc03345a
State	Published - Jan 1 2017

ASJC Scopus subject areas

Catalysis
Electronic, Optical and Magnetic Materials
Ceramics and Composites
Chemistry(all)
Surfaces, Coatings and Films
Metals and Alloys
Materials Chemistry

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10.1039/c7cc03345a

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AU - Hartlieb, K. J.

AU - Peters, A. W.

AU - Wang, T. C.

AU - Deria, P.

AU - Farha, O. K.

AU - Hupp, J. T.

AU - Stoddart, J. F.

PY - 2017/1/1

Y1 - 2017/1/1

N2 - CD-MOF, an extended framework incorporating the C8 symmetric cyclic oligosaccharide, γ-cyclodextrin (γ-CD), is based on the coordination of alkali metal cations to alternating α-1,4-linked d-glucopyranosyl units on the primary and secondary faces of the γ-CD tori. Here, we report the synthesis and characterisation of an amino-functionalised CD-MOF that is isostructural with pristine CD-MOF and adsorbs CO2 permanently.

AB - CD-MOF, an extended framework incorporating the C8 symmetric cyclic oligosaccharide, γ-cyclodextrin (γ-CD), is based on the coordination of alkali metal cations to alternating α-1,4-linked d-glucopyranosyl units on the primary and secondary faces of the γ-CD tori. Here, we report the synthesis and characterisation of an amino-functionalised CD-MOF that is isostructural with pristine CD-MOF and adsorbs CO2 permanently.

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Functionalised cyclodextrin-based metal-organic frameworks

Abstract

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CCDC 1525790: Experimental Crystal Structure Determination

CCDC 1525791: Experimental Crystal Structure Determination

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Functionalised cyclodextrin-based metal-organic frameworks

Abstract

ASJC Scopus subject areas

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Datasets

CCDC 1525790: Experimental Crystal Structure Determination

CCDC 1525791: Experimental Crystal Structure Determination

Cite this