Synthesis in molten gallium provides access to a new class of boron-rich quaternary phases. Its first member, Tb1.8C2Si8(B12)3, represents a new structure type in which B12 icosahedra, eight Si atoms in a staggered ethane-like arrangement, and C2 units are interconnected (see picture; red: Si, blue: B, black: C). The Tb sites have a partial occupation of about 60%.
|Original language||English (US)|
|Number of pages||3|
|Journal||Angewandte Chemie - International Edition|
|State||Published - Mar 1 2002|
- High-temperature chemistry
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