Gas diffusion electrodes, reactor designs and key metrics of low-temperature CO2 electrolysers

David Wakerley, Sarah Lamaison, Joshua Wicks, Auston Clemens, Jeremy Feaster, Daniel Corral, Shaffiq A. Jaffer, Amitava Sarkar, Marc Fontecave, Eric B. Duoss, Sarah Baker, Edward H. Sargent, Thomas F. Jaramillo*, Christopher Hahn

*Corresponding author for this work

Research output: Contribution to journalReview articlepeer-review

256 Scopus citations

Abstract

CO2 emissions can be recycled via low-temperature CO2 electrolysis to generate products such as carbon monoxide, ethanol, ethylene, acetic acid, formic acid and propanol. In recent years, progress has been made towards an industrially relevant performance by leveraging the development of gas diffusion electrodes (GDEs), which enhance the mass transport of reactant gases (for example, CO2) to the active electrocatalyst. Innovations in GDE design have thus set new benchmarks for CO2 conversion activity. In this Review, we discuss GDE-based CO2 electrolysers, in terms of reactor designs, GDE composition and failure modes, to identify the key advances and remaining shortfalls of the technology. This is combined with an overview of the partial current densities, efficiencies and stabilities currently achieved and an outlook on how phenomena such as carbonate formation could influence the future direction of the field. Our aim is to capture insights that can accelerate the development of industrially relevant CO2 electrolysers.

Original languageEnglish (US)
Pages (from-to)130-143
Number of pages14
JournalNature Energy
Volume7
Issue number2
DOIs
StatePublished - Feb 2022

ASJC Scopus subject areas

  • Electronic, Optical and Magnetic Materials
  • Renewable Energy, Sustainability and the Environment
  • Fuel Technology
  • Energy Engineering and Power Technology

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