Gas-Phase Dimerization of Ethylene under Mild Conditions Catalyzed by MOF Materials Containing (bpy)NiII Complexes

Sherzod T. Madrahimov; James R. Gallagher; Guanghui Zhang; Zachary Meinhart; Sergio J. Garibay; Massimiliano Delferro; Jeffrey T. Miller; Omar K. Farha; Joseph T. Hupp; Sonbinh T. Nguyen

doi:10.1021/acscatal.5b01604

Gas-Phase Dimerization of Ethylene under Mild Conditions Catalyzed by MOF Materials Containing (bpy)Ni^II Complexes

Sherzod T. Madrahimov, James R. Gallagher, Guanghui Zhang, Zachary Meinhart, Sergio J. Garibay, Massimiliano Delferro, Jeffrey T. Miller, Omar K. Farha^*, Joseph T. Hupp, Sonbinh T. Nguyen

^*Corresponding author for this work

Chemistry

Research output: Contribution to journal › Article › peer-review

117 Scopus citations

Abstract

NU-1000-(bpy)Ni^II, a highly porous MOF material possessing well-defined (bpy)Ni^II moieties, was prepared through solvent-assisted ligand incorporation (SALI). Treatment with Et₂AlCl affords a single-site catalyst with excellent catalytic activity for ethylene dimerization (intrinsic activity for butenes that is up to an order of magnitude higher than the corresponding (bpy)NiCl₂ homogeneous analogue) and stability (can be reused at least three times). The high porosity of this catalyst results in outstanding levels of activity at ambient temperature in gas-phase ethylene dimerization reactions, both under batch and continuous flow conditions.

Original language	English (US)
Pages (from-to)	6713-6718
Number of pages	6
Journal	ACS Catalysis
Volume	5
Issue number	11
DOIs	https://doi.org/10.1021/acscatal.5b01604
State	Published - Nov 6 2015

Keywords

(bipyridyl)nickel complexes
catalysis
ethylene dimerization
gas-phase reaction
metal-organic framework

ASJC Scopus subject areas

Catalysis
Chemistry(all)

Access to Document

10.1021/acscatal.5b01604

Cite this

@article{ac9256953f464ad3acaadeb4e0f9cfa9,

title = "Gas-Phase Dimerization of Ethylene under Mild Conditions Catalyzed by MOF Materials Containing (bpy)NiII Complexes",

abstract = "NU-1000-(bpy)NiII, a highly porous MOF material possessing well-defined (bpy)NiII moieties, was prepared through solvent-assisted ligand incorporation (SALI). Treatment with Et2AlCl affords a single-site catalyst with excellent catalytic activity for ethylene dimerization (intrinsic activity for butenes that is up to an order of magnitude higher than the corresponding (bpy)NiCl2 homogeneous analogue) and stability (can be reused at least three times). The high porosity of this catalyst results in outstanding levels of activity at ambient temperature in gas-phase ethylene dimerization reactions, both under batch and continuous flow conditions.",

keywords = "(bipyridyl)nickel complexes, catalysis, ethylene dimerization, gas-phase reaction, metal-organic framework",

author = "Madrahimov, {Sherzod T.} and Gallagher, {James R.} and Guanghui Zhang and Zachary Meinhart and Garibay, {Sergio J.} and Massimiliano Delferro and Miller, {Jeffrey T.} and Farha, {Omar K.} and Hupp, {Joseph T.} and Nguyen, {Sonbinh T.}",

note = "Publisher Copyright: {\textcopyright} 2015 American Chemical Society.",

year = "2015",

month = nov,

day = "6",

doi = "10.1021/acscatal.5b01604",

language = "English (US)",

volume = "5",

pages = "6713--6718",

journal = "ACS Catalysis",

issn = "2155-5435",

publisher = "American Chemical Society",

number = "11",

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TY - JOUR

T1 - Gas-Phase Dimerization of Ethylene under Mild Conditions Catalyzed by MOF Materials Containing (bpy)NiII Complexes

AU - Madrahimov, Sherzod T.

AU - Gallagher, James R.

AU - Zhang, Guanghui

AU - Meinhart, Zachary

AU - Garibay, Sergio J.

AU - Delferro, Massimiliano

AU - Miller, Jeffrey T.

AU - Farha, Omar K.

AU - Hupp, Joseph T.

AU - Nguyen, Sonbinh T.

PY - 2015/11/6

Y1 - 2015/11/6

N2 - NU-1000-(bpy)NiII, a highly porous MOF material possessing well-defined (bpy)NiII moieties, was prepared through solvent-assisted ligand incorporation (SALI). Treatment with Et2AlCl affords a single-site catalyst with excellent catalytic activity for ethylene dimerization (intrinsic activity for butenes that is up to an order of magnitude higher than the corresponding (bpy)NiCl2 homogeneous analogue) and stability (can be reused at least three times). The high porosity of this catalyst results in outstanding levels of activity at ambient temperature in gas-phase ethylene dimerization reactions, both under batch and continuous flow conditions.

AB - NU-1000-(bpy)NiII, a highly porous MOF material possessing well-defined (bpy)NiII moieties, was prepared through solvent-assisted ligand incorporation (SALI). Treatment with Et2AlCl affords a single-site catalyst with excellent catalytic activity for ethylene dimerization (intrinsic activity for butenes that is up to an order of magnitude higher than the corresponding (bpy)NiCl2 homogeneous analogue) and stability (can be reused at least three times). The high porosity of this catalyst results in outstanding levels of activity at ambient temperature in gas-phase ethylene dimerization reactions, both under batch and continuous flow conditions.

KW - (bipyridyl)nickel complexes

KW - catalysis

KW - ethylene dimerization

KW - gas-phase reaction

KW - metal-organic framework

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DO - 10.1021/acscatal.5b01604

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JO - ACS Catalysis

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