Generation and Characterization of the First Persistent Platinum(I)-Centered Radical

Yosi Kratish; Arseni Kostenko; Alexander Kaushansky; Boris Tumanskii; Dmitry Bravo-Zhivotovskii; Yitzhak Apeloig

doi:10.1002/anie.201805107

Generation and Characterization of the First Persistent Platinum(I)-Centered Radical

Yosi Kratish, Arseni Kostenko, Alexander Kaushansky, Boris Tumanskii, Dmitry Bravo-Zhivotovskii^*, Yitzhak Apeloig

^*Corresponding author for this work

Chemistry

Research output: Contribution to journal › Article › peer-review

9 Scopus citations

Abstract

The first persistent platinum(I)-centered radical was generated by homolytic cleavage of a Pt−HgSiR₃ bond of a mercury-substituted platinum(II) complex. The Pt^I radical was characterized by EPR spectroscopy, chemical trapping experiments, and density functional theory (DFT) calculations.

Original language	English (US)
Pages (from-to)	8275-8279
Number of pages	5
Journal	Angewandte Chemie - International Edition
Volume	57
Issue number	27
DOIs	https://doi.org/10.1002/anie.201805107
State	Published - Jul 2 2018

Funding

This research was supported by the Israel Science Foundation, the Minerva Foundation in Munich, and the German-Israeli project cooperation (DIP). D.B.-Z. and B.T. are grateful to the Ministry of Immigrant Absorption, State of Israel, for Kamea fellowships.

Keywords

EPR spectroscopy
mercury
mercury–platinum complexes
platinum
radicals

ASJC Scopus subject areas

General Chemistry
Catalysis

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10.1002/anie.201805107

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abstract = "The first persistent platinum(I)-centered radical was generated by homolytic cleavage of a Pt−HgSiR3 bond of a mercury-substituted platinum(II) complex. The PtI radical was characterized by EPR spectroscopy, chemical trapping experiments, and density functional theory (DFT) calculations.",

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AU - Bravo-Zhivotovskii, Dmitry

AU - Apeloig, Yitzhak

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Generation and Characterization of the First Persistent Platinum(I)-Centered Radical

Abstract

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Keywords

ASJC Scopus subject areas

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