Geometrical-Electronic Relationships in the Series PdP2, PdPS, and PdS2

Jeremy K. Burdett; Barry A. Coddens

doi:10.1021/ic00275a035

Geometrical-Electronic Relationships in the Series PdP₂, PdPS, and PdS₂

Jeremy K. Burdett^*, Barry A. Coddens

^*Corresponding author for this work

Chemistry

Research output: Contribution to journal › Article › peer-review

10 Scopus citations

Abstract

The relationship between electronic and geometrical structure is examined for the series Pd(XY), where XY = P₂, PS, and S₂. Population of high-energy orbitals of the parent three-dimensional PdP₂ structure, antibonding between the nonmetal atoms, leads to a gradual breakup of this arrangement with increasing electron count.

Original language	English (US)
Pages (from-to)	418-421
Number of pages	4
Journal	Inorganic chemistry
Volume	27
Issue number	2
DOIs	https://doi.org/10.1021/ic00275a035
State	Published - Jan 1 1988

ASJC Scopus subject areas

Physical and Theoretical Chemistry
Inorganic Chemistry

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10.1021/ic00275a035

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title = "Geometrical-Electronic Relationships in the Series PdP2, PdPS, and PdS2",

abstract = "The relationship between electronic and geometrical structure is examined for the series Pd(XY), where XY = P2, PS, and S2. Population of high-energy orbitals of the parent three-dimensional PdP2 structure, antibonding between the nonmetal atoms, leads to a gradual breakup of this arrangement with increasing electron count.",

author = "Burdett, {Jeremy K.} and Coddens, {Barry A.}",

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AU - Coddens, Barry A.

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N2 - The relationship between electronic and geometrical structure is examined for the series Pd(XY), where XY = P2, PS, and S2. Population of high-energy orbitals of the parent three-dimensional PdP2 structure, antibonding between the nonmetal atoms, leads to a gradual breakup of this arrangement with increasing electron count.

AB - The relationship between electronic and geometrical structure is examined for the series Pd(XY), where XY = P2, PS, and S2. Population of high-energy orbitals of the parent three-dimensional PdP2 structure, antibonding between the nonmetal atoms, leads to a gradual breakup of this arrangement with increasing electron count.

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JO - Inorganic chemistry

JF - Inorganic chemistry

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Geometrical-Electronic Relationships in the Series PdP₂, PdPS, and PdS₂

Abstract

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