Geometrical-Electronic Relationships in the Series PdP2, PdPS, and PdS2

Jeremy K. Burdett*, Barry A. Coddens

*Corresponding author for this work

Research output: Contribution to journalArticlepeer-review

9 Scopus citations

Abstract

The relationship between electronic and geometrical structure is examined for the series Pd(XY), where XY = P2, PS, and S2. Population of high-energy orbitals of the parent three-dimensional PdP2 structure, antibonding between the nonmetal atoms, leads to a gradual breakup of this arrangement with increasing electron count.

Original languageEnglish (US)
Pages (from-to)418-421
Number of pages4
JournalInorganic chemistry
Volume27
Issue number2
DOIs
StatePublished - Jan 1 1988

ASJC Scopus subject areas

  • Physical and Theoretical Chemistry
  • Inorganic Chemistry

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