Geometry of the perxenate ion

Walter C. Hamilton; James A. Ibers; Donald R. Mackenzie

doi:10.1126/science.141.3580.532

Geometry of the perxenate ion

Walter C. Hamilton^*, James A. Ibers, Donald R. Mackenzie

^*Corresponding author for this work

Chemistry

Research output: Contribution to journal › Article › peer-review

5 Scopus citations

Abstract

A three-dimensional x-ray analysis of a crystalline solid of Xe ⁺⁸ formed by the reaction of XeF₆ with sodium hydroxide solution indicates that it is sodium perxenate octahydrate, Na ₄XeO₆ · 8H₂O. The perxenate ion, XeO₆^-4, has approximately a regular octahedral configuration with a mean xenon-oxygen bond length of 1.875 Å.

Original language	English (US)
Pages (from-to)	532-534
Number of pages	3
Journal	Science
Volume	141
Issue number	3580
DOIs	https://doi.org/10.1126/science.141.3580.532
State	Published - 1963

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@article{26714239b39843e8b61e84da9140815b,

title = "Geometry of the perxenate ion",

abstract = "A three-dimensional x-ray analysis of a crystalline solid of Xe +8 formed by the reaction of XeF6 with sodium hydroxide solution indicates that it is sodium perxenate octahydrate, Na 4XeO6 · 8H2O. The perxenate ion, XeO6-4, has approximately a regular octahedral configuration with a mean xenon-oxygen bond length of 1.875 {\AA}.",

author = "Hamilton, {Walter C.} and Ibers, {James A.} and Mackenzie, {Donald R.}",

year = "1963",

doi = "10.1126/science.141.3580.532",

language = "English (US)",

volume = "141",

pages = "532--534",

journal = "Science",

issn = "0036-8075",

publisher = "American Association for the Advancement of Science",

number = "3580",

}

TY - JOUR

T1 - Geometry of the perxenate ion

AU - Hamilton, Walter C.

AU - Ibers, James A.

AU - Mackenzie, Donald R.

PY - 1963

Y1 - 1963

N2 - A three-dimensional x-ray analysis of a crystalline solid of Xe +8 formed by the reaction of XeF6 with sodium hydroxide solution indicates that it is sodium perxenate octahydrate, Na 4XeO6 · 8H2O. The perxenate ion, XeO6-4, has approximately a regular octahedral configuration with a mean xenon-oxygen bond length of 1.875 Å.

AB - A three-dimensional x-ray analysis of a crystalline solid of Xe +8 formed by the reaction of XeF6 with sodium hydroxide solution indicates that it is sodium perxenate octahydrate, Na 4XeO6 · 8H2O. The perxenate ion, XeO6-4, has approximately a regular octahedral configuration with a mean xenon-oxygen bond length of 1.875 Å.

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UR - http://www.scopus.com/inward/citedby.url?scp=34248343751&partnerID=8YFLogxK

U2 - 10.1126/science.141.3580.532

DO - 10.1126/science.141.3580.532

M3 - Article

AN - SCOPUS:34248343751

SN - 0036-8075

VL - 141

SP - 532

EP - 534

JO - Science

JF - Science

IS - 3580

ER -

Geometry of the perxenate ion

Abstract

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