Grain-boundary structure and segregation in Nb3Sn coatings on Nb for high-performance superconducting radiofrequency cavity applications

Jaeyel Lee*, Zugang Mao, Kai He, Zu Hawn Sung, Tiziana Spina, Sung Il Baik, Daniel L. Hall, Matthias Liepe, David N. Seidman, Sam Posen

*Corresponding author for this work

Research output: Contribution to journalArticlepeer-review

2 Scopus citations

Abstract

We report on atomic-scale analyses of grain boundary (GB) structures and segregation in Nb3Sn coatings on Nb, prepared by the vapor-diffusion process, for superconducting radiofrequency (SRF) cavity applications, utilizing atom-probe tomography, high-resolution scanning transmission electron-microscopy and first-principles calculations. We demonstrate that the chemical composition of Nb3Sn GBs is correlated strongly with the diffusion of Sn and Nb at GBs during the coating process. In a sample coated with a relatively large Sn flux, we observe an interfacial width of Sn segregation at a GB of ∼3 nm, with a maximum concentration of ∼35 at.%. After post-annealing at 1100 °C for 3 h, the Sn segregated at GBs disappears and Nb segregation is observed subsequently at GBs, indicating that Nb diffused into the Nb3Sn GBs from the Nb substrate. It is also demonstrated that the amount of Sn segregation in a Nb3Sn coating can be controlled by: (i) Sn flux; and (ii) the temperatures of the Nb substrates and Sn source, which may affect the overall kinetics including GB diffusion of Sn and Nb. An investigation of the correlation between the chemical compositions of GBs and Nb3Sn SRF cavity performance reveals that the Nb3Sn SRF cavities with the best performance (high-quality factors at high accelerating electric-field gradients) do not exhibit Sn segregation at GBs. Our results suggest that the chemical compositions of GBs in Nb3Sn coatings for SRF cavities can be controlled by GB engineering and can be utilized to optimize fabrication of high-quality Nb3Sn coatings for SRF cavities.

Original languageEnglish (US)
Pages (from-to)155-165
Number of pages11
JournalActa Materialia
Volume188
DOIs
StatePublished - Apr 15 2020

Keywords

  • Atom-probe tomography
  • Grain-boundary segregation
  • NbSn
  • Superconducting radio-frequency cavities
  • Transmission electron microscopy

ASJC Scopus subject areas

  • Electronic, Optical and Magnetic Materials
  • Ceramics and Composites
  • Polymers and Plastics
  • Metals and Alloys

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