Growth rates and water stability of 2D boronate ester covalent organic frameworks

Brian J. Smith; Nicky Hwang; Anton D. Chavez; Jennifer L. Novotney; William R. Dichtel

doi:10.1039/c5cc00379b

Growth rates and water stability of 2D boronate ester covalent organic frameworks

Brian J. Smith, Nicky Hwang, Anton D. Chavez, Jennifer L. Novotney, William R. Dichtel^*

^*Corresponding author for this work

Chemistry

Research output: Contribution to journal › Article › peer-review

111 Scopus citations

Abstract

We examine the growth rates, activation energies, and hydrolytic stability of multiple 2D boronate ester covalent organic frameworks by turbidity measurements, observing a 200-fold range in stability. The rate-determining step in boronate ester 2D COF growth is not in-solution condensation, but rather interlayer polymer stacking through a nucleation-elongation process. This journal is

Original language	English (US)
Pages (from-to)	7532-7535
Number of pages	4
Journal	Chemical Communications
Volume	51
Issue number	35
DOIs	https://doi.org/10.1039/c5cc00379b
State	Published - May 1 2015

ASJC Scopus subject areas

Catalysis
Electronic, Optical and Magnetic Materials
Ceramics and Composites
Chemistry(all)
Surfaces, Coatings and Films
Metals and Alloys
Materials Chemistry

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AU - Smith, Brian J.

AU - Hwang, Nicky

AU - Chavez, Anton D.

AU - Novotney, Jennifer L.

AU - Dichtel, William R.

N1 - Publisher Copyright: © The Royal Society of Chemistry 2015.

PY - 2015/5/1

Y1 - 2015/5/1

N2 - We examine the growth rates, activation energies, and hydrolytic stability of multiple 2D boronate ester covalent organic frameworks by turbidity measurements, observing a 200-fold range in stability. The rate-determining step in boronate ester 2D COF growth is not in-solution condensation, but rather interlayer polymer stacking through a nucleation-elongation process. This journal is

AB - We examine the growth rates, activation energies, and hydrolytic stability of multiple 2D boronate ester covalent organic frameworks by turbidity measurements, observing a 200-fold range in stability. The rate-determining step in boronate ester 2D COF growth is not in-solution condensation, but rather interlayer polymer stacking through a nucleation-elongation process. This journal is

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Growth rates and water stability of 2D boronate ester covalent organic frameworks

Abstract

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