Abstract
A novel reaction involving the halide-induced rearrangement of ligands within supramolecular Rh(I) complexes containing hemilabile ligands is presented. Three analogous bis- and trishemilabile ligands have been synthesized to construct bi- and trimetallic Rh(I) macrocyclic complexes. An intentionally added halide source results in the formal rotation of only one hemilabile ligand along the axis that is perpendicular to the plane defined by the aryl backbone of the hemilabile ligands. X-ray structures, as determined by X-ray crystallography, of key intermediates and products are presented.
Original language | English (US) |
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Pages (from-to) | 14316-14317 |
Number of pages | 2 |
Journal | Journal of the American Chemical Society |
Volume | 126 |
Issue number | 44 |
DOIs | |
State | Published - Nov 10 2004 |
ASJC Scopus subject areas
- General Chemistry
- Biochemistry
- Catalysis
- Colloid and Surface Chemistry
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Dive into the research topics of 'Halide-induced supramolecular ligand rearrangement'. Together they form a unique fingerprint.Datasets
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CCDC 255740: Experimental Crystal Structure Determination
Brown, A. M. (Creator), Ovchinnikov, M. V. (Creator), Stern, C. L. (Creator) & Mirkin, C. A. (Creator), Cambridge Crystallographic Data Centre, 2005
DOI: 10.5517/cc8l3pm, http://www.ccdc.cam.ac.uk/services/structure_request?id=doi:10.5517/cc8l3pm&sid=DataCite
Dataset
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CCDC 255742: Experimental Crystal Structure Determination
Brown, A. M. (Creator), Ovchinnikov, M. V. (Creator), Stern, C. L. (Creator) & Mirkin, C. A. (Creator), Cambridge Crystallographic Data Centre, 2005
DOI: 10.5517/cc8l3rp, http://www.ccdc.cam.ac.uk/services/structure_request?id=doi:10.5517/cc8l3rp&sid=DataCite
Dataset
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CCDC 255741: Experimental Crystal Structure Determination
Brown, A. M. (Creator), Ovchinnikov, M. V. (Creator), Stern, C. L. (Creator) & Mirkin, C. A. (Creator), Cambridge Crystallographic Data Centre, 2005
DOI: 10.5517/cc8l3qn, http://www.ccdc.cam.ac.uk/services/structure_request?id=doi:10.5517/cc8l3qn&sid=DataCite
Dataset