Heteroligated metallomacrocycles generated via the weak-link approach

Maxim V. Ovchinnikov; Aaron M. Brown; Xiaogang Liu; Chad A. Mirkin; Lev N. Zakharov; Arnold L. Rheingold

doi:10.1021/ic048785n

Heteroligated metallomacrocycles generated via the weak-link approach

Maxim V. Ovchinnikov, Aaron M. Brown, Xiaogang Liu, Chad A. Mirkin^*, Lev N. Zakharov, Arnold L. Rheingold

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

14 Scopus citations

Abstract

Sequential reaction of two different hemilabile ligands (Ph ₂PCH₂-CH₂X)₂Ar (X = S, Ar = C ₆H₄ or C₆(CH₃)₄; X = NCH₃, Ar = C₆H₄; X = O, Ar = 9,10-C ₁₄H₈) with a Rh(I) metal center resulted in the formation of heteroligated metallomacrocycles in high yield. The specific reaction conditions for each pair of hemilabile ligands are discussed. The solid-state structure of [(1,4-(Ph₂PCH₂CH₂S) ₂C₆H₄)-{1,4-(Ph₂PCH ₂CH₂S)₂C₆(CH₃) ₄}Rh₂](BF₄)₂, as determined by X-ray crystallography, is presented.

Original language	English (US)
Pages (from-to)	8233-8235
Number of pages	3
Journal	Inorganic chemistry
Volume	43
Issue number	26
DOIs	https://doi.org/10.1021/ic048785n
State	Published - Dec 27 2004

ASJC Scopus subject areas

Inorganic Chemistry
Physical and Theoretical Chemistry

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10.1021/ic048785n

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@article{eeb9e074d3e042a0af3eaa86b37bfe22,

title = "Heteroligated metallomacrocycles generated via the weak-link approach",

abstract = "Sequential reaction of two different hemilabile ligands (Ph 2PCH2-CH2X)2Ar (X = S, Ar = C 6H4 or C6(CH3)4; X = NCH3, Ar = C6H4; X = O, Ar = 9,10-C 14H8) with a Rh(I) metal center resulted in the formation of heteroligated metallomacrocycles in high yield. The specific reaction conditions for each pair of hemilabile ligands are discussed. The solid-state structure of [(1,4-(Ph2PCH2CH2S) 2C6H4)-{1,4-(Ph2PCH 2CH2S)2C6(CH3) 4}Rh2](BF4)2, as determined by X-ray crystallography, is presented.",

author = "Ovchinnikov, {Maxim V.} and Brown, {Aaron M.} and Xiaogang Liu and Mirkin, {Chad A.} and Zakharov, {Lev N.} and Rheingold, {Arnold L.}",

year = "2004",

month = dec,

day = "27",

doi = "10.1021/ic048785n",

language = "English (US)",

volume = "43",

pages = "8233--8235",

journal = "Inorganic chemistry",

issn = "0020-1669",

publisher = "American Chemical Society",

number = "26",

}

TY - JOUR

T1 - Heteroligated metallomacrocycles generated via the weak-link approach

AU - Ovchinnikov, Maxim V.

AU - Brown, Aaron M.

AU - Liu, Xiaogang

AU - Mirkin, Chad A.

AU - Zakharov, Lev N.

AU - Rheingold, Arnold L.

PY - 2004/12/27

Y1 - 2004/12/27

N2 - Sequential reaction of two different hemilabile ligands (Ph 2PCH2-CH2X)2Ar (X = S, Ar = C 6H4 or C6(CH3)4; X = NCH3, Ar = C6H4; X = O, Ar = 9,10-C 14H8) with a Rh(I) metal center resulted in the formation of heteroligated metallomacrocycles in high yield. The specific reaction conditions for each pair of hemilabile ligands are discussed. The solid-state structure of [(1,4-(Ph2PCH2CH2S) 2C6H4)-{1,4-(Ph2PCH 2CH2S)2C6(CH3) 4}Rh2](BF4)2, as determined by X-ray crystallography, is presented.

AB - Sequential reaction of two different hemilabile ligands (Ph 2PCH2-CH2X)2Ar (X = S, Ar = C 6H4 or C6(CH3)4; X = NCH3, Ar = C6H4; X = O, Ar = 9,10-C 14H8) with a Rh(I) metal center resulted in the formation of heteroligated metallomacrocycles in high yield. The specific reaction conditions for each pair of hemilabile ligands are discussed. The solid-state structure of [(1,4-(Ph2PCH2CH2S) 2C6H4)-{1,4-(Ph2PCH 2CH2S)2C6(CH3) 4}Rh2](BF4)2, as determined by X-ray crystallography, is presented.

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DO - 10.1021/ic048785n

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SN - 0020-1669

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SP - 8233

EP - 8235

JO - Inorganic chemistry

JF - Inorganic chemistry

IS - 26

ER -

Heteroligated metallomacrocycles generated via the weak-link approach

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CCDC 260590: Experimental Crystal Structure Determination

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Heteroligated metallomacrocycles generated via the weak-link approach

Abstract

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Datasets

CCDC 260590: Experimental Crystal Structure Determination

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