Heteroligated RhI tweezer complexes

Aaron M. Brown*, Maxim V. Ovchinnikov, Chad A. Mirkin

*Corresponding author for this work

Research output: Contribution to journalArticle

36 Scopus citations

Abstract

(Chemical Equation Presented) A halide-induced ligand rearrangement around a RhI center can be used for the preparation of heteroligated tweezer-type complexes. By using a variety of P,S- and P,O-hemilabile ligands, the complexes can be interconverted between four different Rh I-coordination environments (see scheme).

Original languageEnglish (US)
Pages (from-to)4207-4209
Number of pages3
JournalAngewandte Chemie - International Edition
Volume44
Issue number27
DOIs
StatePublished - Jul 4 2005

Keywords

  • Coordination modes
  • Nanostructures
  • Supramolecular chemistry
  • Synthetic methods
  • Transition metals

ASJC Scopus subject areas

  • Catalysis
  • Chemistry(all)

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