Heteroligated RhI tweezer complexes

Aaron M. Brown; Maxim V. Ovchinnikov; Chad A. Mirkin

doi:10.1002/anie.200500689

Heteroligated Rh^I tweezer complexes

Aaron M. Brown^*, Maxim V. Ovchinnikov, Chad A. Mirkin

^*Corresponding author for this work

Chemistry

Research output: Contribution to journal › Article › peer-review

36 Scopus citations

Abstract

(Chemical Equation Presented) A halide-induced ligand rearrangement around a Rh^I center can be used for the preparation of heteroligated tweezer-type complexes. By using a variety of P,S- and P,O-hemilabile ligands, the complexes can be interconverted between four different Rh ^I-coordination environments (see scheme).

Original language	English (US)
Pages (from-to)	4207-4209
Number of pages	3
Journal	Angewandte Chemie - International Edition
Volume	44
Issue number	27
DOIs	https://doi.org/10.1002/anie.200500689
State	Published - Jul 4 2005

Keywords

Coordination modes
Nanostructures
Supramolecular chemistry
Synthetic methods
Transition metals

ASJC Scopus subject areas

Catalysis
Chemistry(all)

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abstract = "(Chemical Equation Presented) A halide-induced ligand rearrangement around a RhI center can be used for the preparation of heteroligated tweezer-type complexes. By using a variety of P,S- and P,O-hemilabile ligands, the complexes can be interconverted between four different Rh I-coordination environments (see scheme).",

keywords = "Coordination modes, Nanostructures, Supramolecular chemistry, Synthetic methods, Transition metals",

author = "Brown, {Aaron M.} and Ovchinnikov, {Maxim V.} and Mirkin, {Chad A.}",

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KW - Supramolecular chemistry

KW - Synthetic methods

KW - Transition metals

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