Abstract
(Chemical Equation Presented) A halide-induced ligand rearrangement around a RhI center can be used for the preparation of heteroligated tweezer-type complexes. By using a variety of P,S- and P,O-hemilabile ligands, the complexes can be interconverted between four different Rh I-coordination environments (see scheme).
Original language | English (US) |
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Pages (from-to) | 4207-4209 |
Number of pages | 3 |
Journal | Angewandte Chemie - International Edition |
Volume | 44 |
Issue number | 27 |
DOIs | |
State | Published - Jul 4 2005 |
Keywords
- Coordination modes
- Nanostructures
- Supramolecular chemistry
- Synthetic methods
- Transition metals
ASJC Scopus subject areas
- Catalysis
- Chemistry(all)
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CCDC 278997: Experimental Crystal Structure Determination
Brown, A. M. (Creator), Ovchinnikov, M. V. (Creator) & Mirkin, C. A. (Creator), Cambridge Crystallographic Data Centre, 2007
DOI: 10.5517/cc9c9xv, http://www.ccdc.cam.ac.uk/services/structure_request?id=doi:10.5517/cc9c9xv&sid=DataCite
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