Heteroligated RhI tweezer complexes

Aaron M. Brown; Maxim V. Ovchinnikov; Chad A. Mirkin

doi:10.1002/anie.200500689

Heteroligated Rh^I tweezer complexes

Aaron M. Brown^*, Maxim V. Ovchinnikov, Chad A. Mirkin

^*Corresponding author for this work

Chemistry

Research output: Contribution to journal › Article › peer-review

37 Scopus citations

Abstract

(Chemical Equation Presented) A halide-induced ligand rearrangement around a Rh^I center can be used for the preparation of heteroligated tweezer-type complexes. By using a variety of P,S- and P,O-hemilabile ligands, the complexes can be interconverted between four different Rh ^I-coordination environments (see scheme).

Original language	English (US)
Pages (from-to)	4207-4209
Number of pages	3
Journal	Angewandte Chemie - International Edition
Volume	44
Issue number	27
DOIs	https://doi.org/10.1002/anie.200500689
State	Published - Jul 4 2005

Keywords

Coordination modes
Nanostructures
Supramolecular chemistry
Synthetic methods
Transition metals

ASJC Scopus subject areas

Catalysis
Chemistry(all)

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10.1002/anie.200500689

Cite this

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title = "Heteroligated RhI tweezer complexes",

abstract = "(Chemical Equation Presented) A halide-induced ligand rearrangement around a RhI center can be used for the preparation of heteroligated tweezer-type complexes. By using a variety of P,S- and P,O-hemilabile ligands, the complexes can be interconverted between four different Rh I-coordination environments (see scheme).",

keywords = "Coordination modes, Nanostructures, Supramolecular chemistry, Synthetic methods, Transition metals",

author = "Brown, {Aaron M.} and Ovchinnikov, {Maxim V.} and Mirkin, {Chad A.}",

year = "2005",

month = jul,

day = "4",

doi = "10.1002/anie.200500689",

language = "English (US)",

volume = "44",

pages = "4207--4209",

journal = "Angewandte Chemie - International Edition",

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publisher = "John Wiley and Sons Ltd",

number = "27",

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T1 - Heteroligated RhI tweezer complexes

AU - Brown, Aaron M.

AU - Ovchinnikov, Maxim V.

AU - Mirkin, Chad A.

PY - 2005/7/4

Y1 - 2005/7/4

N2 - (Chemical Equation Presented) A halide-induced ligand rearrangement around a RhI center can be used for the preparation of heteroligated tweezer-type complexes. By using a variety of P,S- and P,O-hemilabile ligands, the complexes can be interconverted between four different Rh I-coordination environments (see scheme).

AB - (Chemical Equation Presented) A halide-induced ligand rearrangement around a RhI center can be used for the preparation of heteroligated tweezer-type complexes. By using a variety of P,S- and P,O-hemilabile ligands, the complexes can be interconverted between four different Rh I-coordination environments (see scheme).

KW - Coordination modes

KW - Nanostructures

KW - Supramolecular chemistry

KW - Synthetic methods

KW - Transition metals

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U2 - 10.1002/anie.200500689

DO - 10.1002/anie.200500689

M3 - Article

C2 - 15940731

AN - SCOPUS:22144459811

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JO - Angewandte Chemie - International Edition

JF - Angewandte Chemie - International Edition

SN - 1433-7851

IS - 27

ER -

Heteroligated Rh^I tweezer complexes

Abstract

Keywords

ASJC Scopus subject areas

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CCDC 278997: Experimental Crystal Structure Determination

Cite this

Heteroligated RhI tweezer complexes

Abstract

Keywords

ASJC Scopus subject areas

Access to Document

Other files and links

Fingerprint

Datasets

CCDC 278997: Experimental Crystal Structure Determination

Cite this

Heteroligated Rh^I tweezer complexes