Hexachlorotetra-μ3-chloro-tetra-μ 3-tellurooctohexarhenium(III)

Yuri V. Mirnov*, Jason A. Cody, James A. Ibers

*Corresponding author for this work

Research output: Contribution to journalArticlepeer-review

15 Scopus citations

Abstract

The title compound, Re6Te4Cl10, was obtained by reaction of ReCl5 with elemental Te in an evacuated sealed fused silica tube at 773 K. The structure contains two independent Re6 octahedral clusters, each with a crystallographic center of symmetry. The Re atoms are coordinated by four μ3-Te atoms and four μ3-Cl ligands that are equally distributed over the faces of the metal polyhedron. The remaining six Cl atoms are terminal ligands coordinated to the apices of the Re6 octahedron. Distance ranges are: Re-Re 2.618 (1)-2.638(1), Re - μ3-L 2.530 (3)-2.679 (2), Re - Clterminal 2.325 (6)-2.353 (5) Å (L is 50% Te and 50% Cl).

Original languageEnglish (US)
Pages (from-to)281-283
Number of pages3
JournalActa Crystallographica Section C: Crystal Structure Communications
Volume52
Issue number2
DOIs
StatePublished - Feb 15 1996

ASJC Scopus subject areas

  • Biochemistry, Genetics and Molecular Biology(all)

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