TY - JOUR
T1 - High-nanofiller-content graphene oxide-polymer nanocomposites via vacuum-assisted self-assembly
AU - Putz, Karl W.
AU - Compton, Owen C.
AU - Palmeri, Marc J.
AU - Nguyen, Son Binh T.
AU - Brinson, L. Catherine
PY - 2010/10/8
Y1 - 2010/10/8
N2 - Highly ordered, homogeneous polymer nanocomposites of layered graphene oxide are prepared using a vacuum-assisted self-assembly (VASA) technique. In VASA, all components (nanofi ller and polymer) are pre-mixed prior to assembly under a fl ow, making it compatible with either hydrophilic poly(vinyl alcohol) (PVA) or hydrophobic poly(methyl methacrylate) (PMMA) for the preparation of composites with over 50 wt% fi ller. This process is complimentary to layer-by-layer assembly, where the assembling components are required to interact strongly (e.g., via Coulombic attraction). The nanosheets within the VASA-assembled composites exhibit a high degree of order with tunable intersheet spacing, depending on the polymer content. Graphene oxide-PVA nanocomposites, prepared from water, exhibit greatly improved modulus values in comparison to fi lms of either pure PVA or pure graphene oxide. Modulus values for graphene oxide-PMMA nanocomposites, prepared from dimethylformamide, are intermediate to those of the pure components. The differences in structure, modulus, and strength can be attributed to the gallery composition, specifi cally the hydrogen bonding ability of the intercalating species.
AB - Highly ordered, homogeneous polymer nanocomposites of layered graphene oxide are prepared using a vacuum-assisted self-assembly (VASA) technique. In VASA, all components (nanofi ller and polymer) are pre-mixed prior to assembly under a fl ow, making it compatible with either hydrophilic poly(vinyl alcohol) (PVA) or hydrophobic poly(methyl methacrylate) (PMMA) for the preparation of composites with over 50 wt% fi ller. This process is complimentary to layer-by-layer assembly, where the assembling components are required to interact strongly (e.g., via Coulombic attraction). The nanosheets within the VASA-assembled composites exhibit a high degree of order with tunable intersheet spacing, depending on the polymer content. Graphene oxide-PVA nanocomposites, prepared from water, exhibit greatly improved modulus values in comparison to fi lms of either pure PVA or pure graphene oxide. Modulus values for graphene oxide-PMMA nanocomposites, prepared from dimethylformamide, are intermediate to those of the pure components. The differences in structure, modulus, and strength can be attributed to the gallery composition, specifi cally the hydrogen bonding ability of the intercalating species.
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U2 - 10.1002/adfm.201000723
DO - 10.1002/adfm.201000723
M3 - Article
AN - SCOPUS:77957563387
VL - 20
SP - 3322
EP - 3329
JO - Advanced Functional Materials
JF - Advanced Functional Materials
SN - 1616-301X
IS - 19
ER -