Abstract
Herein, we present the discovery of a new high-pressure phase in the Ni-Bi system, β-NiBi, which crystallizes in the TlI structure type. The powerful technique of in situ high-pressure and high-temperature powder X-ray diffraction enabled observation of the formation of β-NiBi and its reversible reconversion to the ambient pressure phase, α-NiBi.
Original language | English (US) |
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Pages (from-to) | 11241-11244 |
Number of pages | 4 |
Journal | Chemical Communications |
Volume | 53 |
Issue number | 81 |
DOIs | |
State | Published - 2017 |
Funding
The authors thank Dr. J. P. S. Walsh for experimental assistance and valuable discussions. The collaborative project between D. E. F., S. D. J., and C. W. is supported by Northwestern University (NU) through the Innovative Initiatives Incubator (I3). Experimental work is supported by the AFOSR (FA95501410358) and (FA95501710247). S. M. C. acknowledges support from the NSF GRFP (DGE-1324585) and a P.EO. Scholar Award. M. A. acknowledges support from the Swiss NSF (P300P2-158407, P300P2-174475). K. M. P. acknowledges NSF DMR-1121262. Y. M. acknowledges the support of DOE-BES/ DMSE (DE-FG02-99ER45775). S. D. J. acknowledges support from NSF (DMR-1508577) and the Carnegie/DOE Alliance Center for providing beamtime at HPCAT. HPCAT operations are supported by DOE-NNSA under Award No. DE-NA0001974, with partial instrumentation funding by NSF. The APS is a U.S. DOE Office of Science User Facility operated for the DOE Office of Science by ANL under Contract No. DE-AC02-06CH11357. This work made use of the IMSERC and EPIC facility of the NUANCE Center at NU, supported by NSF NNCI-1542205; NSF DMR-1121262 (MRSEC program); the Keck Foundation; the State of Illinois; and the IIN.
ASJC Scopus subject areas
- Electronic, Optical and Magnetic Materials
- Ceramics and Composites
- Metals and Alloys
- Materials Chemistry
- Surfaces, Coatings and Films
- General Chemistry
- Catalysis
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CCDC 1575934: Experimental Crystal Structure Determination
Powderly, K. M. (Creator), Clarke, S. M. (Creator), Amsler, M. (Creator), Wolverton, C. (Creator), Malliakas, C. D. (Creator), Meng, Y. (Creator), Jacobsen, S. D. (Creator) & Freedman, D. E. (Creator), Cambridge Crystallographic Data Centre, 2017
DOI: 10.5517/ccdc.csd.cc1pwwl1, http://www.ccdc.cam.ac.uk/services/structure_request?id=doi:10.5517/ccdc.csd.cc1pwwl1&sid=DataCite
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