TY - JOUR
T1 - High-pressure performance of mixed-conducting oxygen electrodes
T2 - Effect of interstitial versus vacancy conductivity
AU - Railsback, Justin
AU - Hughes, Gareth
AU - Mogni, Liliana
AU - Montenegro-Hern�ndez, Alejandra
AU - Barnett, Scott
N1 - Funding Information:
The authors gratefully acknowledge financial support by NSF OISE grant # 1545907, Global Climate and Energy Project (Stanford University) award #51922, and a Northwestern University McCormick School of Engineering Catalyst Award.
Publisher Copyright:
� 2016 The Electrochemical Society. All rights reserved.
PY - 2016
Y1 - 2016
N2 - Electrochemical response was measured as a function of oxygen pressure pO2 up to 10 bar for four different mixed-conducting oxygen electrode materials, the oxygen-vacancy-conducting perovskites (Sm0.5Sr0.5)CoO3 (SSC) and (La0.6Sr0.4)(Co0.2Fe0.8)O3 (LSCF), and the interstitial-oxygen-conducting nickelates Pr2NiO4 (PNO) and Nd2NiO4 (NNO). The impedance spectroscopy (IS) measurements were done on symmetrical cells with either single-phase or two-phase infiltrated electrode structures. The polarization resistance decreased with increasing pressure in all cases, but the nickelates decreased more rapidly than the perovskites. It is proposed that this difference is a direct result of the different pO2 dependences of the defect concentrations - the oxygen vacancy concentration decreases with increasing pO2, whereas interstitial concentrations increase. In order to test this hypothesis, point defect concentrations were calculated for LSCF and NNO single-phase electrodes using the Adler-Lane-Steele model from electrochemical data and electrode microstructural parameters obtained by three-dimensional tomography. The results verified that the observed changes with increasing pO2 can be explained by reasonable decreases in LSCF vacancy concentration and increases in NNO interstitial concentration. These results suggest that nickelate electrodes can be advantageous for pressurized devices.
AB - Electrochemical response was measured as a function of oxygen pressure pO2 up to 10 bar for four different mixed-conducting oxygen electrode materials, the oxygen-vacancy-conducting perovskites (Sm0.5Sr0.5)CoO3 (SSC) and (La0.6Sr0.4)(Co0.2Fe0.8)O3 (LSCF), and the interstitial-oxygen-conducting nickelates Pr2NiO4 (PNO) and Nd2NiO4 (NNO). The impedance spectroscopy (IS) measurements were done on symmetrical cells with either single-phase or two-phase infiltrated electrode structures. The polarization resistance decreased with increasing pressure in all cases, but the nickelates decreased more rapidly than the perovskites. It is proposed that this difference is a direct result of the different pO2 dependences of the defect concentrations - the oxygen vacancy concentration decreases with increasing pO2, whereas interstitial concentrations increase. In order to test this hypothesis, point defect concentrations were calculated for LSCF and NNO single-phase electrodes using the Adler-Lane-Steele model from electrochemical data and electrode microstructural parameters obtained by three-dimensional tomography. The results verified that the observed changes with increasing pO2 can be explained by reasonable decreases in LSCF vacancy concentration and increases in NNO interstitial concentration. These results suggest that nickelate electrodes can be advantageous for pressurized devices.
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U2 - 10.1149/2.1071613jes
DO - 10.1149/2.1071613jes
M3 - Article
AN - SCOPUS:84992195337
SN - 0013-4651
VL - 163
SP - F1433-F1439
JO - Journal of the Electrochemical Society
JF - Journal of the Electrochemical Society
IS - 13
ER -
