Abstract
Perovskite structure can be stabilized through high pressure (HP) synthesis. To illustrate this, the HP synthesis of a new copper-rich layered perovskite, La4Cu3MoO12, which is isotopic with La2CuSnO6 is discussed. When synthesized at ambient pressure, this perovskite forms a structure with remarkably low and unusual coordination of the constituents, which after treatment at high pressure and high temperature adopts new perovskite structure that contains unmixed copper-oxygen planes linked by mixed copper/molybdenum-oxygen planes.
| Original language | English (US) |
|---|---|
| Pages (from-to) | 11518-11519 |
| Number of pages | 2 |
| Journal | Journal of the American Chemical Society |
| Volume | 120 |
| Issue number | 44 |
| DOIs | |
| State | Published - Nov 11 1998 |
ASJC Scopus subject areas
- Catalysis
- Chemistry(all)
- Biochemistry
- Colloid and Surface Chemistry
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Vander Griend, D. A., Boudin, S., Poeppelmeier, K. R., Azuma, M., Toganoh, H., & Takano, M. (1998). High pressure transformation of La4Cu3MoO12 to a layered perovskite [5]. Journal of the American Chemical Society, 120(44), 11518-11519. https://doi.org/10.1021/ja982259b