High propene/propane selectivity in isostructural metal-organic frameworks with high densities of open metal sites

Youn Sang Bae; Chang Yeon Lee; Ki Chul Kim; Omar K. Farha; Peter Nickias; Joseph T. Hupp; Sonbinh T. Nguyen; Randall Q. Snurr

doi:10.1002/anie.201107534

High propene/propane selectivity in isostructural metal-organic frameworks with high densities of open metal sites

Youn Sang Bae, Chang Yeon Lee, Ki Chul Kim, Omar K. Farha, Peter Nickias, Joseph T. Hupp^*, Sonbinh T. Nguyen, Randall Q. Snurr

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

398 Scopus citations

Abstract

Two go in, one comes out: A series of isostructural M-MOF-74 materials (M=Co, Mn, and Mg) with high densities of open metal sites have been examined for the selective adsorption of propene over propane. Co-MOF-74 exhibits the highest thermodynamic C ₃H ₆/C ₃H ₈ selectivity (ca. 45) reported for any MOF to date.

Original language	English (US)
Pages (from-to)	1857-1860
Number of pages	4
Journal	Angewandte Chemie - International Edition
Volume	51
Issue number	8
DOIs	https://doi.org/10.1002/anie.201107534
State	Published - Feb 20 2012

Keywords

adsorption
metal-organic frameworks
open metal sites
propane
propene

ASJC Scopus subject areas

General Chemistry
Catalysis

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10.1002/anie.201107534

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abstract = "Two go in, one comes out: A series of isostructural M-MOF-74 materials (M=Co, Mn, and Mg) with high densities of open metal sites have been examined for the selective adsorption of propene over propane. Co-MOF-74 exhibits the highest thermodynamic C 3H 6/C 3H 8 selectivity (ca. 45) reported for any MOF to date.",

keywords = "adsorption, metal-organic frameworks, open metal sites, propane, propene",

author = "Bae, {Youn Sang} and Lee, {Chang Yeon} and Kim, {Ki Chul} and Farha, {Omar K.} and Peter Nickias and Hupp, {Joseph T.} and Nguyen, {Sonbinh T.} and Snurr, {Randall Q.}",

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AU - Bae, Youn Sang

AU - Lee, Chang Yeon

AU - Kim, Ki Chul

AU - Farha, Omar K.

AU - Nickias, Peter

AU - Hupp, Joseph T.

AU - Nguyen, Sonbinh T.

AU - Snurr, Randall Q.

PY - 2012/2/20

Y1 - 2012/2/20

N2 - Two go in, one comes out: A series of isostructural M-MOF-74 materials (M=Co, Mn, and Mg) with high densities of open metal sites have been examined for the selective adsorption of propene over propane. Co-MOF-74 exhibits the highest thermodynamic C 3H 6/C 3H 8 selectivity (ca. 45) reported for any MOF to date.

AB - Two go in, one comes out: A series of isostructural M-MOF-74 materials (M=Co, Mn, and Mg) with high densities of open metal sites have been examined for the selective adsorption of propene over propane. Co-MOF-74 exhibits the highest thermodynamic C 3H 6/C 3H 8 selectivity (ca. 45) reported for any MOF to date.

KW - adsorption

KW - metal-organic frameworks

KW - open metal sites

KW - propane

KW - propene

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High propene/propane selectivity in isostructural metal-organic frameworks with high densities of open metal sites

Abstract

Keywords

ASJC Scopus subject areas

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