High-Temperature Decomposition of KTiOPO4

M. E. Hagerman, V. L. Kozhevnikov*, K. R. Poeppelmeier

*Corresponding author for this work

Research output: Contribution to journalArticle

19 Scopus citations

Abstract

It has been shown that potassium titanyl phosphate, KTiOPO4, decomposes at elevated temperatures with the evolution of gaseous phosphorus and potassium oxides and formation of solid titanium dioxide. Microscopic investigation and kinetic analysis reveal that the decomposition develops on the surface of KTP microcrystals. A fit of the kinetic curves in the deceleratory period to the Ginstling-Brounshtein equation has shown that the high-temperature decomposition of KTP is limited by diffusion at the reaction interface. The apparent activation energy of the decomposition was determined to be equal to 2.3 ± 0.2 eV.

Original languageEnglish (US)
Pages (from-to)1211-1215
Number of pages5
JournalChemistry of Materials
Volume5
Issue number9
DOIs
StatePublished - Jan 1 1993

ASJC Scopus subject areas

  • Chemistry(all)
  • Chemical Engineering(all)
  • Materials Chemistry

Fingerprint Dive into the research topics of 'High-Temperature Decomposition of KTiOPO<sub>4</sub>'. Together they form a unique fingerprint.

  • Cite this