High Voltage LiNi0.5Mn0.3Co0.2O2/Graphite Cell Cycled at 4.6 V with a FEC/HFDEC-Based Electrolyte

Meinan He, Chi Cheung Su, Zhenxing Feng, Li Zeng, Tianpin Wu, Michael J. Bedzyk, Paul Fenter, Yan Wang, Zhengcheng Zhang*

*Corresponding author for this work

Research output: Contribution to journalArticlepeer-review

41 Scopus citations

Abstract

A high voltage LiNi0.5Mn0.3Co0.2O2/graphite cell with a fluorinated electrolyte formulation 1.0 m LiPF6 fluoroethylene carbonate/bis(2,2,2-trifluoroethyl) carbonate is reported and its electrochemical performance is evaluated at cell voltage of 4.6 V. Comparing with its nonfluorinated electrolyte counterpart, the reported fluorinated one shows much improved Coulombic efficiency and capacity retention when a higher cut-off voltage (4.6 V) is applied. Scanning electron microscopy/energy dispersive X-ray spectroscopy and X-ray photoelectron spectroscopy data clearly demonstrate the superior oxidative stability of the new electrolyte. The structural stability of the bulk cathode materials cycled with different electrolytes is extensively studied by X-ray absorption near edge structure and X-ray diffraction.

Original languageEnglish (US)
JournalAdvanced Energy Materials
Volume7
Issue number15
DOIs
StatePublished - Aug 9 2017

Keywords

  • LiNiMnCoO cathode
  • electrode/electrolyte interface
  • fluorinated electrolytes
  • oxidation stability
  • post-test analysis

ASJC Scopus subject areas

  • Renewable Energy, Sustainability and the Environment
  • Materials Science(all)

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