Highly selective carbon dioxide uptake by [Cu(bpy-n) 2(SiF 6)] (bpy-1 = 4,4′-bipyridine; Bpy-2 = 1,2-bis(4-pyridyl)ethene)

Stephen D. Burd; Shengqian Ma; Jason A. Perman; Benjamin J. Sikora; Randall Q. Snurr; Praveen K. Thallapally; Jian Tian; Lukasz Wojtas; Michael J. Zaworotko

doi:10.1021/ja211340t

Highly selective carbon dioxide uptake by [Cu(bpy-n) ₂(SiF ₆)] (bpy-1 = 4,4′-bipyridine; Bpy-2 = 1,2-bis(4-pyridyl)ethene)

Stephen D. Burd, Shengqian Ma, Jason A. Perman, Benjamin J. Sikora, Randall Q. Snurr, Praveen K. Thallapally, Jian Tian, Lukasz Wojtas, Michael J. Zaworotko^*

^*Corresponding author for this work

Chemical and Biological Engineering

Research output: Contribution to journal › Article › peer-review

302 Scopus citations

Abstract

A previously known class of porous coordination polymer (PCP) of formula [Cu(bpy-n) ₂(SiF ₆)] (bpy-1 = 4,4′-bipyridine; bpy-2 = 1,2-bis(4-pyridyl)ethene) has been studied to assess its selectivity toward CO ₂, CH ₄, N ₂, and H ₂O. Gas sorption measurements reveal that [Cu(bpy-1) ₂(SiF ₆)] exhibits the highest uptake for CO ₂ yet seen at 298 K and 1 atm by a PCP that does not contain open metal sites. Significantly, [Cu(bpy-1) ₂(SiF ₆)] does not exhibit particularly high uptake under the same conditions for CH ₄, N ₂, and, H ₂O, presumably because of its lack of open metal sites. Consequently, at 298 K and 1 atm [Cu(bpy-1) ₂(SiF ₆)] exhibits a relative uptake of CO ₂ over CH ₄ of ca. 10.5:1, the highest value experimentally observed in a compound without open metal sites. [Cu(bpy-2) ₂(SiF ₆)] exhibits larger pores and surface area than [Cu(bpy-1) ₂(SiF ₆)] but retains a high CO ₂/CH ₄ relative uptake of ca. 8:1.

Original language	English (US)
Pages (from-to)	3663-3666
Number of pages	4
Journal	Journal of the American Chemical Society
Volume	134
Issue number	8
DOIs	https://doi.org/10.1021/ja211340t
State	Published - Feb 29 2012

ASJC Scopus subject areas

Catalysis
General Chemistry
Biochemistry
Colloid and Surface Chemistry

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10.1021/ja211340t

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@article{2e022afaae4a44ecb686f9758fa141e9,

title = "Highly selective carbon dioxide uptake by [Cu(bpy-n) 2(SiF 6)] (bpy-1 = 4,4′-bipyridine; Bpy-2 = 1,2-bis(4-pyridyl)ethene)",

abstract = "A previously known class of porous coordination polymer (PCP) of formula [Cu(bpy-n) 2(SiF 6)] (bpy-1 = 4,4′-bipyridine; bpy-2 = 1,2-bis(4-pyridyl)ethene) has been studied to assess its selectivity toward CO 2, CH 4, N 2, and H 2O. Gas sorption measurements reveal that [Cu(bpy-1) 2(SiF 6)] exhibits the highest uptake for CO 2 yet seen at 298 K and 1 atm by a PCP that does not contain open metal sites. Significantly, [Cu(bpy-1) 2(SiF 6)] does not exhibit particularly high uptake under the same conditions for CH 4, N 2, and, H 2O, presumably because of its lack of open metal sites. Consequently, at 298 K and 1 atm [Cu(bpy-1) 2(SiF 6)] exhibits a relative uptake of CO 2 over CH 4 of ca. 10.5:1, the highest value experimentally observed in a compound without open metal sites. [Cu(bpy-2) 2(SiF 6)] exhibits larger pores and surface area than [Cu(bpy-1) 2(SiF 6)] but retains a high CO 2/CH 4 relative uptake of ca. 8:1.",

author = "Burd, {Stephen D.} and Shengqian Ma and Perman, {Jason A.} and Sikora, {Benjamin J.} and Snurr, {Randall Q.} and Thallapally, {Praveen K.} and Jian Tian and Lukasz Wojtas and Zaworotko, {Michael J.}",

year = "2012",

month = feb,

day = "29",

doi = "10.1021/ja211340t",

language = "English (US)",

volume = "134",

pages = "3663--3666",

journal = "Journal of the American Chemical Society",

issn = "0002-7863",

publisher = "American Chemical Society",

number = "8",

}

TY - JOUR

T1 - Highly selective carbon dioxide uptake by [Cu(bpy-n) 2(SiF 6)] (bpy-1 = 4,4′-bipyridine; Bpy-2 = 1,2-bis(4-pyridyl)ethene)

AU - Burd, Stephen D.

AU - Ma, Shengqian

AU - Perman, Jason A.

AU - Sikora, Benjamin J.

AU - Snurr, Randall Q.

AU - Thallapally, Praveen K.

AU - Tian, Jian

AU - Wojtas, Lukasz

AU - Zaworotko, Michael J.

PY - 2012/2/29

Y1 - 2012/2/29

N2 - A previously known class of porous coordination polymer (PCP) of formula [Cu(bpy-n) 2(SiF 6)] (bpy-1 = 4,4′-bipyridine; bpy-2 = 1,2-bis(4-pyridyl)ethene) has been studied to assess its selectivity toward CO 2, CH 4, N 2, and H 2O. Gas sorption measurements reveal that [Cu(bpy-1) 2(SiF 6)] exhibits the highest uptake for CO 2 yet seen at 298 K and 1 atm by a PCP that does not contain open metal sites. Significantly, [Cu(bpy-1) 2(SiF 6)] does not exhibit particularly high uptake under the same conditions for CH 4, N 2, and, H 2O, presumably because of its lack of open metal sites. Consequently, at 298 K and 1 atm [Cu(bpy-1) 2(SiF 6)] exhibits a relative uptake of CO 2 over CH 4 of ca. 10.5:1, the highest value experimentally observed in a compound without open metal sites. [Cu(bpy-2) 2(SiF 6)] exhibits larger pores and surface area than [Cu(bpy-1) 2(SiF 6)] but retains a high CO 2/CH 4 relative uptake of ca. 8:1.

AB - A previously known class of porous coordination polymer (PCP) of formula [Cu(bpy-n) 2(SiF 6)] (bpy-1 = 4,4′-bipyridine; bpy-2 = 1,2-bis(4-pyridyl)ethene) has been studied to assess its selectivity toward CO 2, CH 4, N 2, and H 2O. Gas sorption measurements reveal that [Cu(bpy-1) 2(SiF 6)] exhibits the highest uptake for CO 2 yet seen at 298 K and 1 atm by a PCP that does not contain open metal sites. Significantly, [Cu(bpy-1) 2(SiF 6)] does not exhibit particularly high uptake under the same conditions for CH 4, N 2, and, H 2O, presumably because of its lack of open metal sites. Consequently, at 298 K and 1 atm [Cu(bpy-1) 2(SiF 6)] exhibits a relative uptake of CO 2 over CH 4 of ca. 10.5:1, the highest value experimentally observed in a compound without open metal sites. [Cu(bpy-2) 2(SiF 6)] exhibits larger pores and surface area than [Cu(bpy-1) 2(SiF 6)] but retains a high CO 2/CH 4 relative uptake of ca. 8:1.

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DO - 10.1021/ja211340t

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AN - SCOPUS:84857737694

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VL - 134

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EP - 3666

JO - Journal of the American Chemical Society

JF - Journal of the American Chemical Society

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ER -

Highly selective carbon dioxide uptake by [Cu(bpy-n) ₂(SiF ₆)] (bpy-1 = 4,4′-bipyridine; Bpy-2 = 1,2-bis(4-pyridyl)ethene)

Abstract

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CCDC 878759: Experimental Crystal Structure Determination

CCDC 878760: Experimental Crystal Structure Determination

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Highly selective carbon dioxide uptake by [Cu(bpy-n) 2(SiF 6)] (bpy-1 = 4,4′-bipyridine; Bpy-2 = 1,2-bis(4-pyridyl)ethene)

Abstract

ASJC Scopus subject areas

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Datasets

CCDC 878759: Experimental Crystal Structure Determination

CCDC 878760: Experimental Crystal Structure Determination

Cite this

Highly selective carbon dioxide uptake by [Cu(bpy-n) ₂(SiF ₆)] (bpy-1 = 4,4′-bipyridine; Bpy-2 = 1,2-bis(4-pyridyl)ethene)