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Highly stereoselective formal [3 + 3] cycloaddition of enals and azomethine imines catalyzed by N-heterocyclic carbenes
Audrey Chan,
Karl A. Scheidt
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Corresponding author for this work
Chemistry
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peer-review
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Keyphrases
Cycloaddition
100%
N-heterocyclic Carbenes
100%
Highly Stereoselective
100%
Enals
100%
Azomethine Imines
100%
Unsaturated Aldehyde
75%
Aromatics
50%
Pyridazinone
50%
Alcohol
25%
Esters
25%
Amides
25%
Amines
25%
Homoenolate
25%
Catalyzed Reaction
25%
Diastereoselectivity
25%
Six-membered Rings
25%
Nucleophilic
25%
Alkyl
25%
Carbonyl
25%
Excellent Yields
25%
NHC-catalyzed
25%
Ring Opening
25%
Benzimidazolium Salts
25%
Mesityl
25%
Intramolecular Acylation
25%
Chemistry
N-Heterocyclic Carbene
100%
Cycloaddition
100%
Azomethine
100%
Imine
100%
Aldehyde
75%
Pyridazinone
50%
Catalysis
25%
Diastereoselectivity
25%
Ring Opening Reaction
25%
Carboxamide
25%
six membered rings
25%
Acylation
25%