Hole mobility in DNA a tracts

Frederick D. Lewis; Huihe Zhu; Pierre Daublain; Boiko Cohen; Michael R. Wasielewski

doi:10.1002/anie.200603455

Hole mobility in DNA a tracts

Frederick D. Lewis^*, Huihe Zhu, Pierre Daublain, Boiko Cohen, Michael R. Wasielewski

^*Corresponding author for this work

Chemistry

Research output: Contribution to journal › Article › peer-review

75 Scopus citations

Abstract

Whole scheme of things: The kinetics and efficiency of photoinduced hole transport across DNA A tracts with 1-7 base pairs have been determined from femtosecond transient absorption spectroscopic data. These values are strongly distance dependent over the first four base pairs, but are relatively insensitive to distance at longer distances. These kinetic results (□, ■) parallel the DNA-strand-cleavage results of Giese et al. (○, Black circle). (Graph Presented).

Original language	English (US)
Pages (from-to)	7982-7985
Number of pages	4
Journal	Angewandte Chemie - International Edition
Volume	45
Issue number	47
DOIs	https://doi.org/10.1002/anie.200603455
State	Published - Dec 4 2006

Keywords

DNA conjugates
Electron transfer
Hole hopping
Hole injection
Hole trapping

ASJC Scopus subject areas

Catalysis
Chemistry(all)

Access to Document

10.1002/anie.200603455

Cite this

@article{2845b7a10a8647269598d417c5c07a00,

title = "Hole mobility in DNA a tracts",

abstract = "Whole scheme of things: The kinetics and efficiency of photoinduced hole transport across DNA A tracts with 1-7 base pairs have been determined from femtosecond transient absorption spectroscopic data. These values are strongly distance dependent over the first four base pairs, but are relatively insensitive to distance at longer distances. These kinetic results (□, ■) parallel the DNA-strand-cleavage results of Giese et al. (○, Black circle). (Graph Presented).",

keywords = "DNA conjugates, Electron transfer, Hole hopping, Hole injection, Hole trapping",

author = "Lewis, {Frederick D.} and Huihe Zhu and Pierre Daublain and Boiko Cohen and Wasielewski, {Michael R.}",

year = "2006",

month = dec,

day = "4",

doi = "10.1002/anie.200603455",

language = "English (US)",

volume = "45",

pages = "7982--7985",

journal = "Angewandte Chemie - International Edition",

issn = "1433-7851",

publisher = "John Wiley and Sons Ltd",

number = "47",

}

TY - JOUR

T1 - Hole mobility in DNA a tracts

AU - Lewis, Frederick D.

AU - Zhu, Huihe

AU - Daublain, Pierre

AU - Cohen, Boiko

AU - Wasielewski, Michael R.

PY - 2006/12/4

Y1 - 2006/12/4

N2 - Whole scheme of things: The kinetics and efficiency of photoinduced hole transport across DNA A tracts with 1-7 base pairs have been determined from femtosecond transient absorption spectroscopic data. These values are strongly distance dependent over the first four base pairs, but are relatively insensitive to distance at longer distances. These kinetic results (□, ■) parallel the DNA-strand-cleavage results of Giese et al. (○, Black circle). (Graph Presented).

AB - Whole scheme of things: The kinetics and efficiency of photoinduced hole transport across DNA A tracts with 1-7 base pairs have been determined from femtosecond transient absorption spectroscopic data. These values are strongly distance dependent over the first four base pairs, but are relatively insensitive to distance at longer distances. These kinetic results (□, ■) parallel the DNA-strand-cleavage results of Giese et al. (○, Black circle). (Graph Presented).

KW - DNA conjugates

KW - Electron transfer

KW - Hole hopping

KW - Hole injection

KW - Hole trapping

UR - http://www.scopus.com/inward/record.url?scp=33845500080&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=33845500080&partnerID=8YFLogxK

U2 - 10.1002/anie.200603455

DO - 10.1002/anie.200603455

M3 - Article

C2 - 17072927

AN - SCOPUS:33845500080

SN - 1433-7851

VL - 45

SP - 7982

EP - 7985

JO - Angewandte Chemie - International Edition

JF - Angewandte Chemie - International Edition

IS - 47

ER -

Hole mobility in DNA a tracts

Abstract

Keywords

ASJC Scopus subject areas

Access to Document

Other files and links

Fingerprint

Cite this