Hydrocarbon oxidation reactions on oxide surfaces

Kenneth Poeppelmeier; Jason D. Pless; Natasha Erdman; Donggeun Ko; Laurence Marks; Peter Stair

Hydrocarbon oxidation reactions on oxide surfaces

Kenneth Poeppelmeier^*, Jason D. Pless, Natasha Erdman, Donggeun Ko, Laurence Marks, Peter Stair

^*Corresponding author for this work

Research output: Contribution to journal › Conference article

Abstract

Heterogeneous catalytic oxidations of hydrocarbons that employ metal oxide catalysts, which avoid the production of CO ₂, will be increasingly importance in the field of industrial chemistry. Metal oxides convert short chain alkanes, e.g., butane, to alkenes and water by oxidative dehydrogenation. Thin films of Mg ₃(VO ₄) ₂ is an excellent model catalyst. A study on the surface chemistry and the reversible reduction and oxidation of the underlying lattice is carried out. To grow high quality single crystals, the traveling solvent zone method is used. An atmosphere of flowing oxygen is required to stabilize V ⁵⁺ and grow crystals with few(er) defects. The growth of Mg ₃(VO ₄) single crystals are presented. This is an abstract of a paper presented at the 222nd ACS National Meting (Chicago, IL 8/26-30/2001).

Original language	English (US)
Pages (from-to)	372-373
Number of pages	2
Journal	ACS Division of Environmental Chemistry, Preprints
Volume	41
Issue number	2
State	Published - Dec 1 2001
Event	222nd ACS National Meeting - Chicago, IL, United States Duration: Aug 26 2001 → Aug 30 2001

ASJC Scopus subject areas

Chemical Engineering(all)

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Poeppelmeier, K., Pless, J. D., Erdman, N., Ko, D., Marks, L., & Stair, P. (2001). Hydrocarbon oxidation reactions on oxide surfaces. ACS Division of Environmental Chemistry, Preprints, 41(2), 372-373.

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abstract = "Heterogeneous catalytic oxidations of hydrocarbons that employ metal oxide catalysts, which avoid the production of CO 2, will be increasingly importance in the field of industrial chemistry. Metal oxides convert short chain alkanes, e.g., butane, to alkenes and water by oxidative dehydrogenation. Thin films of Mg 3(VO 4) 2 is an excellent model catalyst. A study on the surface chemistry and the reversible reduction and oxidation of the underlying lattice is carried out. To grow high quality single crystals, the traveling solvent zone method is used. An atmosphere of flowing oxygen is required to stabilize V 5+ and grow crystals with few(er) defects. The growth of Mg 3(VO 4) single crystals are presented. This is an abstract of a paper presented at the 222nd ACS National Meting (Chicago, IL 8/26-30/2001).",

author = "Kenneth Poeppelmeier and Pless, {Jason D.} and Natasha Erdman and Donggeun Ko and Laurence Marks and Peter Stair",

year = "2001",

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journal = "ACS Division of Environmental Chemistry, Preprints",

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T1 - Hydrocarbon oxidation reactions on oxide surfaces

AU - Poeppelmeier, Kenneth

AU - Pless, Jason D.

AU - Erdman, Natasha

AU - Ko, Donggeun

AU - Marks, Laurence

AU - Stair, Peter

PY - 2001/12/1

Y1 - 2001/12/1

N2 - Heterogeneous catalytic oxidations of hydrocarbons that employ metal oxide catalysts, which avoid the production of CO 2, will be increasingly importance in the field of industrial chemistry. Metal oxides convert short chain alkanes, e.g., butane, to alkenes and water by oxidative dehydrogenation. Thin films of Mg 3(VO 4) 2 is an excellent model catalyst. A study on the surface chemistry and the reversible reduction and oxidation of the underlying lattice is carried out. To grow high quality single crystals, the traveling solvent zone method is used. An atmosphere of flowing oxygen is required to stabilize V 5+ and grow crystals with few(er) defects. The growth of Mg 3(VO 4) single crystals are presented. This is an abstract of a paper presented at the 222nd ACS National Meting (Chicago, IL 8/26-30/2001).

AB - Heterogeneous catalytic oxidations of hydrocarbons that employ metal oxide catalysts, which avoid the production of CO 2, will be increasingly importance in the field of industrial chemistry. Metal oxides convert short chain alkanes, e.g., butane, to alkenes and water by oxidative dehydrogenation. Thin films of Mg 3(VO 4) 2 is an excellent model catalyst. A study on the surface chemistry and the reversible reduction and oxidation of the underlying lattice is carried out. To grow high quality single crystals, the traveling solvent zone method is used. An atmosphere of flowing oxygen is required to stabilize V 5+ and grow crystals with few(er) defects. The growth of Mg 3(VO 4) single crystals are presented. This is an abstract of a paper presented at the 222nd ACS National Meting (Chicago, IL 8/26-30/2001).

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