Hydrothermal Synthesis of K2PdSe10. Coexistence of Two Large Interpenetrating Three-Dimensional Frameworks of [Pd(Se4)2]2- and [Pd(Se6)2]2-

Kang Woo Kim; Mercouri G. Kanatzidis

doi:10.1021/ja00038a063

Hydrothermal Synthesis of K₂PdSe₁₀. Coexistence of Two Large Interpenetrating Three-Dimensional Frameworks of [Pd(Se₄)₂]^2- and [Pd(Se₆)₂]^2-

Kang Woo Kim, Mercouri G. Kanatzidis^*

^*Corresponding author for this work

Chemistry

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120 Scopus citations

Abstract

The hydrothermal reaction of PdCl₂ with K₂Se₄ in the presence of different KOH and water in the 1:5:5:40 ratio produced K₂[PdSe₁₀] (I), the first metal polychalcogenide compound containing two interpenetrating three-dimensional frameworks. The black rectangular chunky crystals of I are insoluble in water and most organic solvents. They crystallize in the orthorhombic space group I2₁2₁2₁ (no. 24) with a = 15.872 (9) Å, b = 15.922 (9) Å, c = 12.885 (8) Å, V = 3256 (6) Å³. I is composed of two independent interpenetrating 3D diamond-like frameworks of [Pd(Se₄)₂]^2- and [Pd(Se₆)₂]^2-. Each framework contains large tunnels running parallel to the a-and b-crystallographic axes. The coordination geometry around Pd is square-planar. The average Pd-Se and Se-Se distances are 2.462 (5) and 2.35 (2) Å, respectively. The closest distances between K⁺ ions and Se atoms are in the range of 3.27 (2) and 3.75 (2) Å.

Original language	English (US)
Pages (from-to)	4878-4883
Number of pages	6
Journal	Journal of the American Chemical Society
Volume	114
Issue number	12
DOIs	https://doi.org/10.1021/ja00038a063
State	Published - Jun 1 1992

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Catalysis
Chemistry(all)
Biochemistry
Colloid and Surface Chemistry

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title = "Hydrothermal Synthesis of K2PdSe10. Coexistence of Two Large Interpenetrating Three-Dimensional Frameworks of [Pd(Se4)2]2- and [Pd(Se6)2]2-",

abstract = "The hydrothermal reaction of PdCl2 with K2Se4 in the presence of different KOH and water in the 1:5:5:40 ratio produced K2[PdSe10] (I), the first metal polychalcogenide compound containing two interpenetrating three-dimensional frameworks. The black rectangular chunky crystals of I are insoluble in water and most organic solvents. They crystallize in the orthorhombic space group I212121 (no. 24) with a = 15.872 (9) {\AA}, b = 15.922 (9) {\AA}, c = 12.885 (8) {\AA}, V = 3256 (6) {\AA}3. I is composed of two independent interpenetrating 3D diamond-like frameworks of [Pd(Se4)2]2- and [Pd(Se6)2]2-. Each framework contains large tunnels running parallel to the a-and b-crystallographic axes. The coordination geometry around Pd is square-planar. The average Pd-Se and Se-Se distances are 2.462 (5) and 2.35 (2) {\AA}, respectively. The closest distances between K+ ions and Se atoms are in the range of 3.27 (2) and 3.75 (2) {\AA}.",

author = "Kim, {Kang Woo} and Kanatzidis, {Mercouri G.}",

year = "1992",

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AU - Kanatzidis, Mercouri G.

PY - 1992/6/1

Y1 - 1992/6/1

N2 - The hydrothermal reaction of PdCl2 with K2Se4 in the presence of different KOH and water in the 1:5:5:40 ratio produced K2[PdSe10] (I), the first metal polychalcogenide compound containing two interpenetrating three-dimensional frameworks. The black rectangular chunky crystals of I are insoluble in water and most organic solvents. They crystallize in the orthorhombic space group I212121 (no. 24) with a = 15.872 (9) Å, b = 15.922 (9) Å, c = 12.885 (8) Å, V = 3256 (6) Å3. I is composed of two independent interpenetrating 3D diamond-like frameworks of [Pd(Se4)2]2- and [Pd(Se6)2]2-. Each framework contains large tunnels running parallel to the a-and b-crystallographic axes. The coordination geometry around Pd is square-planar. The average Pd-Se and Se-Se distances are 2.462 (5) and 2.35 (2) Å, respectively. The closest distances between K+ ions and Se atoms are in the range of 3.27 (2) and 3.75 (2) Å.

AB - The hydrothermal reaction of PdCl2 with K2Se4 in the presence of different KOH and water in the 1:5:5:40 ratio produced K2[PdSe10] (I), the first metal polychalcogenide compound containing two interpenetrating three-dimensional frameworks. The black rectangular chunky crystals of I are insoluble in water and most organic solvents. They crystallize in the orthorhombic space group I212121 (no. 24) with a = 15.872 (9) Å, b = 15.922 (9) Å, c = 12.885 (8) Å, V = 3256 (6) Å3. I is composed of two independent interpenetrating 3D diamond-like frameworks of [Pd(Se4)2]2- and [Pd(Se6)2]2-. Each framework contains large tunnels running parallel to the a-and b-crystallographic axes. The coordination geometry around Pd is square-planar. The average Pd-Se and Se-Se distances are 2.462 (5) and 2.35 (2) Å, respectively. The closest distances between K+ ions and Se atoms are in the range of 3.27 (2) and 3.75 (2) Å.

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Hydrothermal Synthesis of K₂PdSe₁₀. Coexistence of Two Large Interpenetrating Three-Dimensional Frameworks of [Pd(Se₄)₂]^2- and [Pd(Se₆)₂]^2-

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