Abstract
An image field theory of surface enhanced Raman spectroscopy is used to study the dependence of Raman intensities on light frequency, nature of the adsorbate and metal, electrode potential, scattering angle and light polarization. Although the image field enhancement (IFE) theory is at best a crude approximation to the true enhancement mechanism, we do find quite reasonable agreement between the IFE predictions and most existing experimental results.
| Original language | English (US) |
|---|---|
| Pages (from-to) | 425-438 |
| Number of pages | 14 |
| Journal | Surface Science |
| Volume | 101 |
| Issue number | 1-3 |
| DOIs | |
| State | Published - Jan 1 1980 |
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ASJC Scopus subject areas
- Condensed Matter Physics
- Surfaces and Interfaces
- Surfaces, Coatings and Films
- Materials Chemistry
Cite this
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Image field theory of enhanced Raman scattering by molecules adsorbed on metal surfaces : Detailed comparison with experimental results. / Schatz, George C; Van Duyne, Richard P.
In: Surface Science, Vol. 101, No. 1-3, 01.01.1980, p. 425-438.Research output: Contribution to journal › Article
TY - JOUR
T1 - Image field theory of enhanced Raman scattering by molecules adsorbed on metal surfaces
T2 - Detailed comparison with experimental results
AU - Schatz, George C
AU - Van Duyne, Richard P
PY - 1980/1/1
Y1 - 1980/1/1
N2 - An image field theory of surface enhanced Raman spectroscopy is used to study the dependence of Raman intensities on light frequency, nature of the adsorbate and metal, electrode potential, scattering angle and light polarization. Although the image field enhancement (IFE) theory is at best a crude approximation to the true enhancement mechanism, we do find quite reasonable agreement between the IFE predictions and most existing experimental results.
AB - An image field theory of surface enhanced Raman spectroscopy is used to study the dependence of Raman intensities on light frequency, nature of the adsorbate and metal, electrode potential, scattering angle and light polarization. Although the image field enhancement (IFE) theory is at best a crude approximation to the true enhancement mechanism, we do find quite reasonable agreement between the IFE predictions and most existing experimental results.
UR - http://www.scopus.com/inward/record.url?scp=0041426617&partnerID=8YFLogxK
UR - http://www.scopus.com/inward/citedby.url?scp=0041426617&partnerID=8YFLogxK
U2 - 10.1016/0039-6028(80)90639-1
DO - 10.1016/0039-6028(80)90639-1
M3 - Article
VL - 101
SP - 425
EP - 438
JO - Surface Science
JF - Surface Science
SN - 0039-6028
IS - 1-3
ER -