TY - JOUR
T1 - Image field theory of enhanced Raman scattering by molecules adsorbed on metal surfaces
T2 - Detailed comparison with experimental results
AU - Schatz, George C.
AU - Van Duyne, Richard P.
N1 - Funding Information:
We acknowledge support from the Office of Naval Research (Contract N00014-79-C-0794) and the National Science Foundation (Grant CHE-7824866). We also acknowledge helpful discussion with C. Allen and S. Schultz.
PY - 1980/12
Y1 - 1980/12
N2 - An image field theory of surface enhanced Raman spectroscopy is used to study the dependence of Raman intensities on light frequency, nature of the adsorbate and metal, electrode potential, scattering angle and light polarization. Although the image field enhancement (IFE) theory is at best a crude approximation to the true enhancement mechanism, we do find quite reasonable agreement between the IFE predictions and most existing experimental results.
AB - An image field theory of surface enhanced Raman spectroscopy is used to study the dependence of Raman intensities on light frequency, nature of the adsorbate and metal, electrode potential, scattering angle and light polarization. Although the image field enhancement (IFE) theory is at best a crude approximation to the true enhancement mechanism, we do find quite reasonable agreement between the IFE predictions and most existing experimental results.
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U2 - 10.1016/0039-6028(80)90639-1
DO - 10.1016/0039-6028(80)90639-1
M3 - Article
AN - SCOPUS:0041426617
VL - 101
SP - 425
EP - 438
JO - Surface Science
JF - Surface Science
SN - 0039-6028
IS - 1-3
ER -