Image field theory of enhanced Raman scattering by molecules adsorbed on metal surfaces: Detailed comparison with experimental results

George C. Schatz; Richard P. Van Duyne

doi:10.1016/0039-6028(80)90639-1

Image field theory of enhanced Raman scattering by molecules adsorbed on metal surfaces: Detailed comparison with experimental results

George C. Schatz^*, Richard P. Van Duyne

^*Corresponding author for this work

Chemistry

Research output: Contribution to journal › Article

60 Scopus citations

Abstract

An image field theory of surface enhanced Raman spectroscopy is used to study the dependence of Raman intensities on light frequency, nature of the adsorbate and metal, electrode potential, scattering angle and light polarization. Although the image field enhancement (IFE) theory is at best a crude approximation to the true enhancement mechanism, we do find quite reasonable agreement between the IFE predictions and most existing experimental results.

Original language	English (US)
Pages (from-to)	425-438
Number of pages	14
Journal	Surface Science
Volume	101
Issue number	1-3
DOIs	https://doi.org/10.1016/0039-6028(80)90639-1
State	Published - Dec 1980

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ASJC Scopus subject areas

Condensed Matter Physics
Surfaces and Interfaces
Surfaces, Coatings and Films
Materials Chemistry

Cite this

Schatz, G. C., & Van Duyne, R. P. (1980). Image field theory of enhanced Raman scattering by molecules adsorbed on metal surfaces: Detailed comparison with experimental results. Surface Science, 101(1-3), 425-438. https://doi.org/10.1016/0039-6028(80)90639-1

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Access to Document

10.1016/0039-6028(80)90639-1