TY - JOUR
T1 - Imine-linked microporous polymer organic frameworks
AU - Pandey, Prativa
AU - Katsoulidis, Alexandros P.
AU - Eryazici, Ibrahim
AU - Wu, Yuyang
AU - Kanatzidis, Mercouri
AU - Nguyen, SonBinh
PY - 2010/9/14
Y1 - 2010/9/14
N2 - Imine-linked microporous polymer organic frameworks (POFs) were synthesized via Schiff base condensation between 1,3,5-triformylbenzene and several readily available diamine monomers. Our facile, one-pot approach results in quantitative yields of POFs with the flexibility to incorporate several functional groups in their pores for tuning the interaction of their surface with different guest molecules. Synthesized POFs exhibit high specific surface areas (up to 1500 m2 g-1) as well as high isosteric heats of H2 adsorption (up to 8.2 kJ mol-1).
AB - Imine-linked microporous polymer organic frameworks (POFs) were synthesized via Schiff base condensation between 1,3,5-triformylbenzene and several readily available diamine monomers. Our facile, one-pot approach results in quantitative yields of POFs with the flexibility to incorporate several functional groups in their pores for tuning the interaction of their surface with different guest molecules. Synthesized POFs exhibit high specific surface areas (up to 1500 m2 g-1) as well as high isosteric heats of H2 adsorption (up to 8.2 kJ mol-1).
UR - http://www.scopus.com/inward/record.url?scp=77956407473&partnerID=8YFLogxK
UR - http://www.scopus.com/inward/citedby.url?scp=77956407473&partnerID=8YFLogxK
U2 - 10.1021/cm101157w
DO - 10.1021/cm101157w
M3 - Article
AN - SCOPUS:77956407473
VL - 22
SP - 4974
EP - 4979
JO - Chemistry of Materials
JF - Chemistry of Materials
SN - 0897-4756
IS - 17
ER -