Imine-linked microporous polymer organic frameworks

Prativa Pandey; Alexandros P. Katsoulidis; Ibrahim Eryazici; Yuyang Wu; Mercouri G. Kanatzidis; Sonbinh T. Nguyen

doi:10.1021/cm101157w

Imine-linked microporous polymer organic frameworks

Prativa Pandey, Alexandros P. Katsoulidis, Ibrahim Eryazici, Yuyang Wu, Mercouri G. Kanatzidis, Sonbinh T. Nguyen

Chemistry

Research output: Contribution to journal › Article › peer-review

184 Scopus citations

Abstract

Imine-linked microporous polymer organic frameworks (POFs) were synthesized via Schiff base condensation between 1,3,5-triformylbenzene and several readily available diamine monomers. Our facile, one-pot approach results in quantitative yields of POFs with the flexibility to incorporate several functional groups in their pores for tuning the interaction of their surface with different guest molecules. Synthesized POFs exhibit high specific surface areas (up to 1500 m² g^-1) as well as high isosteric heats of H₂ adsorption (up to 8.2 kJ mol^-1).

Original language	English (US)
Pages (from-to)	4974-4979
Number of pages	6
Journal	Chemistry of Materials
Volume	22
Issue number	17
DOIs	https://doi.org/10.1021/cm101157w
State	Published - Sep 14 2010

ASJC Scopus subject areas

Chemistry(all)
Chemical Engineering(all)
Materials Chemistry

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abstract = "Imine-linked microporous polymer organic frameworks (POFs) were synthesized via Schiff base condensation between 1,3,5-triformylbenzene and several readily available diamine monomers. Our facile, one-pot approach results in quantitative yields of POFs with the flexibility to incorporate several functional groups in their pores for tuning the interaction of their surface with different guest molecules. Synthesized POFs exhibit high specific surface areas (up to 1500 m2 g-1) as well as high isosteric heats of H2 adsorption (up to 8.2 kJ mol-1).",

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AU - Pandey, Prativa

AU - Katsoulidis, Alexandros P.

AU - Eryazici, Ibrahim

AU - Wu, Yuyang

AU - Kanatzidis, Mercouri G.

AU - Nguyen, Sonbinh T.

PY - 2010/9/14

Y1 - 2010/9/14

N2 - Imine-linked microporous polymer organic frameworks (POFs) were synthesized via Schiff base condensation between 1,3,5-triformylbenzene and several readily available diamine monomers. Our facile, one-pot approach results in quantitative yields of POFs with the flexibility to incorporate several functional groups in their pores for tuning the interaction of their surface with different guest molecules. Synthesized POFs exhibit high specific surface areas (up to 1500 m2 g-1) as well as high isosteric heats of H2 adsorption (up to 8.2 kJ mol-1).

AB - Imine-linked microporous polymer organic frameworks (POFs) were synthesized via Schiff base condensation between 1,3,5-triformylbenzene and several readily available diamine monomers. Our facile, one-pot approach results in quantitative yields of POFs with the flexibility to incorporate several functional groups in their pores for tuning the interaction of their surface with different guest molecules. Synthesized POFs exhibit high specific surface areas (up to 1500 m2 g-1) as well as high isosteric heats of H2 adsorption (up to 8.2 kJ mol-1).

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Imine-linked microporous polymer organic frameworks

Abstract

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