Impact of Drying and Effective Stresses on the Pore Space and Microstructure of Mudrocks

Amer Deirieh, Irene Y. Chang, Brendan Casey, Derk Joester, John T. Germaine*

*Corresponding author for this work

Research output: Contribution to journalArticle

Abstract

The evolution of the pore space of mudrocks induced by drying shrinkage and effective stresses is of importance to several areas of research. Drying is a prerequisite for most mudrock characterization methods, while effective stresses have a direct impact on mudrocks properties such as permeability, compressibility, and strength. Mercury porosimetry intrusion has been widely utilized to show that drying shrinkage and effective stresses lead to the collapse of large pores only (~ > 50 nm), while small pores (~ < 50 nm) remain unaffected. However, the validity of mercury porosimetry intrusion-derived pore size distributions is greatly doubted in the literature due to the fact that most pores in mudrocks are not directly accessible to the surrounding mercury. This study follows a different approach by utilizing a suite of methods including imaging by transmission electron microscopy and scanning electron microscopy at cryogenic temperature after high-pressure freezing (cryoSEM), and gravimetric porosity measurements to investigate the influence of volumetric changes on the pore space of mudrocks. Contrary to previously published results, we show that volumetric changes induced by drying and effective stresses lead to the collapse of pores of all sizes. Furthermore, we show that porosity measured from SEM images is dependent on SEM resolution and reveals only a fraction of the actual porosity. These results provide valuable insights used to interpret the results of characterization methods requiring drying and modeling of effective stress influence on the properties of mudrocks.

Original languageEnglish (US)
Pages (from-to)4290-4304
Number of pages15
JournalJournal of Geophysical Research: Solid Earth
Volume124
Issue number5
DOIs
StatePublished - May 1 2019

Fingerprint

pore space
effective stress
drying
mudstone
microstructure
Drying
porosity
Microstructure
Mercury
Porosity
scanning electron microscopy
Scanning electron microscopy
imaging method
Compressibility
shrinkage
intrusion
Freezing
Cryogenics
Pore size
compressibility

Keywords

  • CryoSEM
  • Gulf of Mexico mudrocks
  • drying shrinkage
  • effective stress application
  • mudrock porosity
  • pore space evolution

ASJC Scopus subject areas

  • Geophysics
  • Geochemistry and Petrology
  • Earth and Planetary Sciences (miscellaneous)
  • Space and Planetary Science

Cite this

Deirieh, Amer ; Chang, Irene Y. ; Casey, Brendan ; Joester, Derk ; Germaine, John T. / Impact of Drying and Effective Stresses on the Pore Space and Microstructure of Mudrocks. In: Journal of Geophysical Research: Solid Earth. 2019 ; Vol. 124, No. 5. pp. 4290-4304.
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Impact of Drying and Effective Stresses on the Pore Space and Microstructure of Mudrocks. / Deirieh, Amer; Chang, Irene Y.; Casey, Brendan; Joester, Derk; Germaine, John T.

In: Journal of Geophysical Research: Solid Earth, Vol. 124, No. 5, 01.05.2019, p. 4290-4304.

Research output: Contribution to journalArticle

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