Improved resolution and detection of 31P-Tl J-couplings at 21 T in 31P magic angle spinning NMR spectra of inorganic compounds containing Tl/Bi/P/S

Matthew A. Gave; Kermit M. Johnson; Mercouri G. Kanatzidis; David P. Weliky

doi:10.1016/j.ssnmr.2007.11.002

Improved resolution and detection of ³¹P-Tl J-couplings at 21 T in ³¹P magic angle spinning NMR spectra of inorganic compounds containing Tl/Bi/P/S

Matthew A. Gave, Kermit M. Johnson, Mercouri G. Kanatzidis, David P. Weliky^*

^*Corresponding author for this work

Chemistry

Research output: Contribution to journal › Article › peer-review

Abstract

For crystalline compounds containing Tl, Bi, P, and S, greatly improved chemical shift resolution was observed in ³¹P magic angle spinning spectra obtained at 21 T relative to spectra obtained at 9.4 T. In Hz units, the spectral linewidths were not strongly dependent on the applied field, which may be a result of a significant contribution to the linewidths from transverse relaxation. Comparison of the spectra at the two different fields confirmed that spectral splittings were due to two-bond phosphorus-thallium J-coupling. These results suggest that ultra-high field may be a useful tool to improve spectral resolution of spin frac(1, 2) nuclei in crystalline inorganic compounds.

Original language	English (US)
Pages (from-to)	12-15
Number of pages	4
Journal	Solid State Nuclear Magnetic Resonance
Volume	33
Issue number	1-2
DOIs	https://doi.org/10.1016/j.ssnmr.2007.11.002
State	Published - Jan 2008

Keywords

900 MHz
Chalcophosphate
High field NMR
Inorganic
J-coupling
P
Resolution
Solid state NMR
Thiophosphate
Ultra-high field NMR

ASJC Scopus subject areas

Radiation
Chemistry(all)
Nuclear and High Energy Physics
Instrumentation

Access to Document

10.1016/j.ssnmr.2007.11.002

Cite this

@article{a0888a3ad8364fa58133911db6f49da3,

title = "Improved resolution and detection of 31P-Tl J-couplings at 21 T in 31P magic angle spinning NMR spectra of inorganic compounds containing Tl/Bi/P/S",

abstract = "For crystalline compounds containing Tl, Bi, P, and S, greatly improved chemical shift resolution was observed in 31P magic angle spinning spectra obtained at 21 T relative to spectra obtained at 9.4 T. In Hz units, the spectral linewidths were not strongly dependent on the applied field, which may be a result of a significant contribution to the linewidths from transverse relaxation. Comparison of the spectra at the two different fields confirmed that spectral splittings were due to two-bond phosphorus-thallium J-coupling. These results suggest that ultra-high field may be a useful tool to improve spectral resolution of spin frac(1, 2) nuclei in crystalline inorganic compounds.",

keywords = "900 MHz, Chalcophosphate, High field NMR, Inorganic, J-coupling, P, Resolution, Solid state NMR, Thiophosphate, Ultra-high field NMR",

author = "Gave, {Matthew A.} and Johnson, {Kermit M.} and Kanatzidis, {Mercouri G.} and Weliky, {David P.}",

note = "Funding Information: Access and assistance with the 900 MHz NMR was provided by Dr. Aizhuo Liu and by the Michigan Center for Structural Biology and financial support was provided by NSF DMR-0443783. Copyright: Copyright 2008 Elsevier B.V., All rights reserved.",

year = "2008",

month = jan,

doi = "10.1016/j.ssnmr.2007.11.002",

language = "English (US)",

volume = "33",

pages = "12--15",

journal = "Solid State Nuclear Magnetic Resonance",

issn = "0926-2040",

publisher = "Elsevier",

number = "1-2",

}

TY - JOUR

T1 - Improved resolution and detection of 31P-Tl J-couplings at 21 T in 31P magic angle spinning NMR spectra of inorganic compounds containing Tl/Bi/P/S

AU - Gave, Matthew A.

AU - Johnson, Kermit M.

AU - Kanatzidis, Mercouri G.

AU - Weliky, David P.

N1 - Funding Information: Access and assistance with the 900 MHz NMR was provided by Dr. Aizhuo Liu and by the Michigan Center for Structural Biology and financial support was provided by NSF DMR-0443783. Copyright: Copyright 2008 Elsevier B.V., All rights reserved.

PY - 2008/1

Y1 - 2008/1

N2 - For crystalline compounds containing Tl, Bi, P, and S, greatly improved chemical shift resolution was observed in 31P magic angle spinning spectra obtained at 21 T relative to spectra obtained at 9.4 T. In Hz units, the spectral linewidths were not strongly dependent on the applied field, which may be a result of a significant contribution to the linewidths from transverse relaxation. Comparison of the spectra at the two different fields confirmed that spectral splittings were due to two-bond phosphorus-thallium J-coupling. These results suggest that ultra-high field may be a useful tool to improve spectral resolution of spin frac(1, 2) nuclei in crystalline inorganic compounds.

AB - For crystalline compounds containing Tl, Bi, P, and S, greatly improved chemical shift resolution was observed in 31P magic angle spinning spectra obtained at 21 T relative to spectra obtained at 9.4 T. In Hz units, the spectral linewidths were not strongly dependent on the applied field, which may be a result of a significant contribution to the linewidths from transverse relaxation. Comparison of the spectra at the two different fields confirmed that spectral splittings were due to two-bond phosphorus-thallium J-coupling. These results suggest that ultra-high field may be a useful tool to improve spectral resolution of spin frac(1, 2) nuclei in crystalline inorganic compounds.

KW - 900 MHz

KW - Chalcophosphate

KW - High field NMR

KW - Inorganic

KW - J-coupling

KW - P

KW - Resolution

KW - Solid state NMR

KW - Thiophosphate

KW - Ultra-high field NMR

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U2 - 10.1016/j.ssnmr.2007.11.002

DO - 10.1016/j.ssnmr.2007.11.002

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EP - 15

JO - Solid State Nuclear Magnetic Resonance

JF - Solid State Nuclear Magnetic Resonance

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