In situ intercalative polymerization as a route to layered conducting polymer-inorganic matrix microlaminates. Polypyrrole and polythiophene in FeOCl

M. G. Kanatzidis; M. Hubbard; L. M. Tonge; T. J. Marks; H. O. Marcy; C. R. Kannewurf

doi:10.1016/0379-6779(89)90504-3

In situ intercalative polymerization as a route to layered conducting polymer-inorganic matrix microlaminates. Polypyrrole and polythiophene in FeOCl

M. G. Kanatzidis^*, M. Hubbard, L. M. Tonge, T. J. Marks, H. O. Marcy, C. R. Kannewurf

^*Corresponding author for this work

Chemistry

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Abstract

The reaction of FeOCl with pyrrole and 2,2′-bithiophene proceeds with concomitant intercalation and oxidative polymerization of these heterocycles within the FeOCl van der Waals gap to yield (polypyrrole)_0.34FeOCl and (polythiophene)_0.28FeOCl, respectively. This process is accompanied by a simultaneous and structurally appropriate expansion in the FeOCl interlayer separation. Chemical, infrared spectroscopic, ⁵⁷Fe Mo{combining double acute accent}ssbauer spectroscopic, and variable temperature charge transport data (four-probe conductivity, thermoelectric power) are in accord with this structural model.

Original language	English (US)
Pages (from-to)	89-95
Number of pages	7
Journal	Synthetic Metals
Volume	28
Issue number	1-2
DOIs	https://doi.org/10.1016/0379-6779(89)90504-3
State	Published - Jan 30 1989

ASJC Scopus subject areas

Electronic, Optical and Magnetic Materials
Condensed Matter Physics
Mechanics of Materials
Mechanical Engineering
Metals and Alloys
Materials Chemistry

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10.1016/0379-6779(89)90504-3

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title = "In situ intercalative polymerization as a route to layered conducting polymer-inorganic matrix microlaminates. Polypyrrole and polythiophene in FeOCl",

abstract = "The reaction of FeOCl with pyrrole and 2,2′-bithiophene proceeds with concomitant intercalation and oxidative polymerization of these heterocycles within the FeOCl van der Waals gap to yield (polypyrrole)0.34FeOCl and (polythiophene)0.28FeOCl, respectively. This process is accompanied by a simultaneous and structurally appropriate expansion in the FeOCl interlayer separation. Chemical, infrared spectroscopic, 57Fe Mo{combining double acute accent}ssbauer spectroscopic, and variable temperature charge transport data (four-probe conductivity, thermoelectric power) are in accord with this structural model.",

author = "Kanatzidis, {M. G.} and M. Hubbard and Tonge, {L. M.} and Marks, {T. J.} and Marcy, {H. O.} and Kannewurf, {C. R.}",

note = "Funding Information: ACKNOWLEDGEMENTS This research was supported at Northwestern by the Office of Naval Research and the Northwestern Materials Research Center (NSF-MRL Grant DMR 85-20280).",

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doi = "10.1016/0379-6779(89)90504-3",

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T1 - In situ intercalative polymerization as a route to layered conducting polymer-inorganic matrix microlaminates. Polypyrrole and polythiophene in FeOCl

AU - Kanatzidis, M. G.

AU - Hubbard, M.

AU - Tonge, L. M.

AU - Marks, T. J.

AU - Marcy, H. O.

AU - Kannewurf, C. R.

N1 - Funding Information: ACKNOWLEDGEMENTS This research was supported at Northwestern by the Office of Naval Research and the Northwestern Materials Research Center (NSF-MRL Grant DMR 85-20280).

PY - 1989/1/30

Y1 - 1989/1/30

N2 - The reaction of FeOCl with pyrrole and 2,2′-bithiophene proceeds with concomitant intercalation and oxidative polymerization of these heterocycles within the FeOCl van der Waals gap to yield (polypyrrole)0.34FeOCl and (polythiophene)0.28FeOCl, respectively. This process is accompanied by a simultaneous and structurally appropriate expansion in the FeOCl interlayer separation. Chemical, infrared spectroscopic, 57Fe Mo{combining double acute accent}ssbauer spectroscopic, and variable temperature charge transport data (four-probe conductivity, thermoelectric power) are in accord with this structural model.

AB - The reaction of FeOCl with pyrrole and 2,2′-bithiophene proceeds with concomitant intercalation and oxidative polymerization of these heterocycles within the FeOCl van der Waals gap to yield (polypyrrole)0.34FeOCl and (polythiophene)0.28FeOCl, respectively. This process is accompanied by a simultaneous and structurally appropriate expansion in the FeOCl interlayer separation. Chemical, infrared spectroscopic, 57Fe Mo{combining double acute accent}ssbauer spectroscopic, and variable temperature charge transport data (four-probe conductivity, thermoelectric power) are in accord with this structural model.

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IS - 1-2

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In situ intercalative polymerization as a route to layered conducting polymer-inorganic matrix microlaminates. Polypyrrole and polythiophene in FeOCl

Abstract

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