Incorporation of an A1/A2-difunctionalized pillar[5]arene into a metal-organic framework

Nathan L. Strutt; David Fairen-Jimenez; Julien Iehl; Marianne B. Lalonde; Randall Q. Snurr; Omar K. Farha; Joseph T. Hupp; J. Fraser Stoddart

doi:10.1021/ja3082523

Incorporation of an A1/A2-difunctionalized pillar[5]arene into a metal-organic framework

Nathan L. Strutt, David Fairen-Jimenez, Julien Iehl, Marianne B. Lalonde, Randall Q. Snurr, Omar K. Farha, Joseph T. Hupp, J. Fraser Stoddart^*

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

251 Scopus citations

Abstract

An efficient synthetic route to an A1/A2-difunctionalized pillar[5]arene containing resolvable planar chirality has been developed and the arene employed as a strut in the synthesis of P5A-MOF-1, which has been demonstrated by X-ray powder diffraction analysis-supported by modeling-to be isoreticular with MOF-5. This metal-organic framework has an active domain that expresses good and selective uptake of neutral and positively charged electron-poor aromatic guests, which effect color changes of the cubic crystals from faint yellow to deep orange, arising from charge transfer between the guests and active domain of P5A-MOF-1.

Original language	English (US)
Pages (from-to)	17436-17439
Number of pages	4
Journal	Journal of the American Chemical Society
Volume	134
Issue number	42
DOIs	https://doi.org/10.1021/ja3082523
State	Published - Oct 24 2012

ASJC Scopus subject areas

Catalysis
General Chemistry
Biochemistry
Colloid and Surface Chemistry

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10.1021/ja3082523

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title = "Incorporation of an A1/A2-difunctionalized pillar[5]arene into a metal-organic framework",

abstract = "An efficient synthetic route to an A1/A2-difunctionalized pillar[5]arene containing resolvable planar chirality has been developed and the arene employed as a strut in the synthesis of P5A-MOF-1, which has been demonstrated by X-ray powder diffraction analysis-supported by modeling-to be isoreticular with MOF-5. This metal-organic framework has an active domain that expresses good and selective uptake of neutral and positively charged electron-poor aromatic guests, which effect color changes of the cubic crystals from faint yellow to deep orange, arising from charge transfer between the guests and active domain of P5A-MOF-1.",

author = "Strutt, {Nathan L.} and David Fairen-Jimenez and Julien Iehl and Lalonde, {Marianne B.} and Snurr, {Randall Q.} and Farha, {Omar K.} and Hupp, {Joseph T.} and Stoddart, {J. Fraser}",

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AU - Strutt, Nathan L.

AU - Fairen-Jimenez, David

AU - Iehl, Julien

AU - Lalonde, Marianne B.

AU - Snurr, Randall Q.

AU - Farha, Omar K.

AU - Hupp, Joseph T.

AU - Stoddart, J. Fraser

PY - 2012/10/24

Y1 - 2012/10/24

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AB - An efficient synthetic route to an A1/A2-difunctionalized pillar[5]arene containing resolvable planar chirality has been developed and the arene employed as a strut in the synthesis of P5A-MOF-1, which has been demonstrated by X-ray powder diffraction analysis-supported by modeling-to be isoreticular with MOF-5. This metal-organic framework has an active domain that expresses good and selective uptake of neutral and positively charged electron-poor aromatic guests, which effect color changes of the cubic crystals from faint yellow to deep orange, arising from charge transfer between the guests and active domain of P5A-MOF-1.

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Incorporation of an A1/A2-difunctionalized pillar[5]arene into a metal-organic framework

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CCDC 896924: Experimental Crystal Structure Determination

CCDC 896923: Experimental Crystal Structure Determination

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Incorporation of an A1/A2-difunctionalized pillar[5]arene into a metal-organic framework

Abstract

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Datasets

CCDC 896924: Experimental Crystal Structure Determination

CCDC 896923: Experimental Crystal Structure Determination

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