Infrared multiphoton isomerization of cis- and trans-1,3,5-hexatriene

Frederick D Lewis*, Peter A. Teng, Eric Weltz

*Corresponding author for this work

Research output: Contribution to journalArticlepeer-review

11 Scopus citations

Abstract

The laser-induced infrared multiphoton isomerization reactions of cis- and trans-1,3,5-hexatriene have been investigated. Excitation of the trans isomer produces vibrationally excited cis molecules possessing sufficient energy to undergo electrocyclic ring closure to 1,3-cyclohexadiene. The ratio of primary (cis) to secondary (cyclohexadiene) products is dependent upon laser fluence and buffer gas pressure. Excitation of the cis isomer produces both trans and cyclohexadiene products. The fluence dependence of the product ratio is in accord with RRKM calculations for competing reactions of the highly excited (70-100 kcal/mol) cis parent isomer.

Original languageEnglish (US)
Pages (from-to)1666-1668
Number of pages3
JournalJournal of Physical Chemistry
Volume87
Issue number10
DOIs
StatePublished - Jan 1 1983

ASJC Scopus subject areas

  • Engineering(all)
  • Physical and Theoretical Chemistry

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