Insertion of Tetrafluoroethylene into the Fe-Fe Bond of (µ(SCH3)Fe(CO)3)2, Its Thermal Rearrangement to a Bridging Carbene Ligand, and the Transformation of the Carbene to a Perfluoromethylcarbyne Ligand. Structures of µ(SCH3)2µ(C2F4)Fe2(CO)6 and µ(SCH3)2µ(FCCF3)Fe2(CO)6 at -162 °C

J. J. Bonnet, R. Mathieu, R. Poilblanc, James A Ibers

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Chemistry