Interfacial reactions in Ni/CoSb3 couples at 450 °c

Wei An Chen, Sinn Wen Chen*, Ssu Ming Tseng, Haw Wen Hsiao, Yang Yuan Chen, G. Jeffrey Snyder, Yinglu Tang

*Corresponding author for this work

Research output: Contribution to journalLetter

12 Scopus citations

Abstract

CoSb3-based alloys are promising thermoelectric materials, and nickel is commonly used as barrier layer. This study examines interfacial reactions in the Ni/Sb and Ni/CoSb3 couples reacted at 723 K. Three reaction phases, Ni5Sb2, NiSb and NiSb2, are found in the Ni/Sb couples. In the Ni/CoSb3 couples, the reaction path is Ni/Ni5Sb2/(Co,Ni)Sb/CoSb3. Nickel is the fastest diffusion species, and the growth front is at the (Co,Ni)Sb/CoSb3 interface. Co is the second fastest diffusion species, and a Co-rich region is formed at the Ni phase. The reaction layers grow with longer reaction time. Their average growth rates in the Ni/Sb and Ni/CoSb3 couples reacted for 20 h are 1.1 μm/h and 1.0 μm/h, respectively.

Original languageEnglish (US)
Pages (from-to)500-504
Number of pages5
JournalJournal of Alloys and Compounds
Volume632
DOIs
StatePublished - May 25 2015

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Keywords

  • CoSb
  • Interfacial reaction
  • Ni
  • Thermoelectric

ASJC Scopus subject areas

  • Mechanics of Materials
  • Mechanical Engineering
  • Metals and Alloys
  • Materials Chemistry

Cite this

Chen, W. A., Chen, S. W., Tseng, S. M., Hsiao, H. W., Chen, Y. Y., Snyder, G. J., & Tang, Y. (2015). Interfacial reactions in Ni/CoSb3 couples at 450 °c. Journal of Alloys and Compounds, 632, 500-504. https://doi.org/10.1016/j.jallcom.2015.01.176