Interplays of excited state structures and dynamics in copper(I) diimine complexes: Implications and perspectives

Michael W. Mara, Kelly A. Fransted, Lin X. Chen*

*Corresponding author for this work

Research output: Contribution to journalReview articlepeer-review

108 Scopus citations

Abstract

Although they were discovered almost four decades ago, Cu(I) diimine complexes have emerged as a group of transition metal complexes that can play important roles in solar energy conversion and utilization, and have potential to replace the quintessential ruthenium polypyridyl complexes as light sensitizers, electron donors and catalytic centers. This review includes some recent photophysical studies and transient structural studies of Cu(I) diimine complexes using ultrafast optical transient absorption and emission as well as X-ray transient absorption spectroscopy. The main focus is on identifying the key structural factors that influence the excited-state properties, such as structural reorganization, intersystem crossing and solvent quenching, with these relatively new techniques on the ultrafast time scales. Ultimately, these structural factors can be used to rationally control the energetics and dynamics of the MLCT state during the light conversion processes. This insight will serve as guidance for material design using Cu(I) diimine complexes as building blocks.

Original languageEnglish (US)
Pages (from-to)2-18
Number of pages17
JournalCoordination Chemistry Reviews
Volume282-283
DOIs
StatePublished - Jan 1 2015

Keywords

  • Copper diimine
  • Excited state structure
  • Solar energy conversion
  • Transition metal complexes
  • Ultrafast X-ray absorption
  • Ultrafast optical transient absorption

ASJC Scopus subject areas

  • Physical and Theoretical Chemistry
  • Inorganic Chemistry
  • Materials Chemistry

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