Ion-Exchangeable Molybdenum Sulfide Porous Chalcogel: Gas Adsorption and Capture of Iodine and Mercury

Kota S. Subrahmanyam, Christos D. Malliakas, Debajit Sarma, Gerasimos S. Armatas, Jinsong Wu, Mercouri G. Kanatzidis*

*Corresponding author for this work

Research output: Contribution to journalArticle

72 Scopus citations

Abstract

We report the synthesis of ion-exchangeable molybdenum sulfide chalcogel through an oxidative coupling process, using (NH4)2MoS4 and iodine. After supercritical drying, the MoSx amorphous aerogel shows a large surface area up to 370 m2/g with a broad range of pore sizes. X-ray photoelectron spectroscopic and pair distribution function analyses reveal that Mo6+ species undergo reduction during network assembly to produce Mo4+-containing species where the chalcogel network consists of [Mo3S13] building blocks comprising triangular Mo metal clusters and S22- units. The optical band gap of the brown-black chalcogel is 1.36 eV. The ammonium sites present in the molybdenum sulfide chalcogel network are ion-exchangeable with K+ and Cs+ ions. The molybdenum sulfide aerogel exhibits high adsorption selectivities for CO2 and C2H6 over H2 and CH4. The aerogel also possesses high affinity for iodine and mercury.

Original languageEnglish (US)
Pages (from-to)13943-13948
Number of pages6
JournalJournal of the American Chemical Society
Volume137
Issue number43
DOIs
StatePublished - Nov 4 2015

ASJC Scopus subject areas

  • Catalysis
  • Chemistry(all)
  • Biochemistry
  • Colloid and Surface Chemistry

Fingerprint Dive into the research topics of 'Ion-Exchangeable Molybdenum Sulfide Porous Chalcogel: Gas Adsorption and Capture of Iodine and Mercury'. Together they form a unique fingerprint.

  • Cite this