Ion-pairing in polyether solid electrolytes and its influence on ion transport

B. L. Papke; R. Dupon; M. A. Ratner; D. F. Shriver

doi:10.1016/0167-2738(81)90346-5

Ion-pairing in polyether solid electrolytes and its influence on ion transport

B. L. Papke^*, R. Dupon, M. A. Ratner, D. F. Shriver

^*Corresponding author for this work

Chemistry

Research output: Contribution to journal › Article › peer-review

76 Scopus citations

Abstract

Vibrational spectroscopic and conductivity data are presented for complexes of NaBF₄ and NaBH₄ with poly(ethylene oxide). These studies indicate that extensive contact ion pairing occurs in the NaBH₄ complex but not in the NaBH₄ complex. As a result the ionic conductivity is considerably lower in the NaBH₄ complex, due to trapping of the mobile sodium cations by the anion. The effect of salt stoichiometry on the conductivity behavior is also reported.

Original language	English (US)
Pages (from-to)	685-688
Number of pages	4
Journal	Solid State Ionics
Volume	5
Issue number	C
DOIs	https://doi.org/10.1016/0167-2738(81)90346-5
State	Published - Oct 1981

Funding

Acknowledgments. This work was supported by the National Science Foundation through the Northwestern University Materials Research Center (Grant No. DMR 79-23573) and by the Office of Naval Research. We thank Dr. D. H. Whitmore, Dr. M. B. Armand and Dr. P. V. Wright for a stimulating exchange of information.

ASJC Scopus subject areas

General Chemistry
General Materials Science
Condensed Matter Physics

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10.1016/0167-2738(81)90346-5

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title = "Ion-pairing in polyether solid electrolytes and its influence on ion transport",

abstract = "Vibrational spectroscopic and conductivity data are presented for complexes of NaBF4 and NaBH4 with poly(ethylene oxide). These studies indicate that extensive contact ion pairing occurs in the NaBH4 complex but not in the NaBH4 complex. As a result the ionic conductivity is considerably lower in the NaBH4 complex, due to trapping of the mobile sodium cations by the anion. The effect of salt stoichiometry on the conductivity behavior is also reported.",

author = "Papke, {B. L.} and R. Dupon and Ratner, {M. A.} and Shriver, {D. F.}",

note = "Funding Information: Acknowledgments. This work was supported by the National Science Foundation through the Northwestern University Materials Research Center (Grant No. DMR 79-23573) and by the Office of Naval Research. We thank Dr. D. H. Whitmore, Dr. M. B. Armand and Dr. P. V. Wright for a stimulating exchange of information.",

year = "1981",

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doi = "10.1016/0167-2738(81)90346-5",

language = "English (US)",

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T1 - Ion-pairing in polyether solid electrolytes and its influence on ion transport

AU - Papke, B. L.

AU - Dupon, R.

AU - Ratner, M. A.

AU - Shriver, D. F.

N1 - Funding Information: Acknowledgments. This work was supported by the National Science Foundation through the Northwestern University Materials Research Center (Grant No. DMR 79-23573) and by the Office of Naval Research. We thank Dr. D. H. Whitmore, Dr. M. B. Armand and Dr. P. V. Wright for a stimulating exchange of information.

PY - 1981/10

Y1 - 1981/10

N2 - Vibrational spectroscopic and conductivity data are presented for complexes of NaBF4 and NaBH4 with poly(ethylene oxide). These studies indicate that extensive contact ion pairing occurs in the NaBH4 complex but not in the NaBH4 complex. As a result the ionic conductivity is considerably lower in the NaBH4 complex, due to trapping of the mobile sodium cations by the anion. The effect of salt stoichiometry on the conductivity behavior is also reported.

AB - Vibrational spectroscopic and conductivity data are presented for complexes of NaBF4 and NaBH4 with poly(ethylene oxide). These studies indicate that extensive contact ion pairing occurs in the NaBH4 complex but not in the NaBH4 complex. As a result the ionic conductivity is considerably lower in the NaBH4 complex, due to trapping of the mobile sodium cations by the anion. The effect of salt stoichiometry on the conductivity behavior is also reported.

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JO - Solid State Ionics

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ER -

Ion-pairing in polyether solid electrolytes and its influence on ion transport

Abstract

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